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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 2
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Original Articles

CAN-Mediated Oxidative Free Radical Reactions in an Ionic Liquid

, &
Pages 213-222 | Received 10 Dec 2001, Published online: 21 Aug 2006
 

Abstract

Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon–carbon bond-forming reactions.

Acknowledgment

We thank the EU (under the ERASMUS scheme) for funding.

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