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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 6
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Original Articles

Ion Exchange Catalysis in Oxidation of Organic Compounds with KMnO4

Ahmad Shaabani Department of Chemistry, Shahid Beheshti University, Tehran, IranCorrespondence[email protected]
,
Fatemeh Teimouri Department of Chemistry, Shahid Beheshti University, Tehran, Iran
&
Donald G. Lee Department of Chemistry, University of Regina, Regina, Canada
Pages 1057-1065 | Received 18 Feb 2001, Published online: 17 Aug 2006
 
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Abstract

The oxidation of organic compounds under ion exchange resin (IER) catalysis by KMnO4 has been studied in CH2Cl2 under reflux conditions. Secondary aliphatic and aromatic alcohols are converted to ketones, alkyl arenes and sulfides oxidized to corresponding ketones and sulfones, respectively, and thiols undergo oxidative coupling reactions to give disulfides. The experimental procedure is simple and products are easily isolated in good yields.

Acknowledgment

Financial support by the Research Council of Shahid Beheshti University is acknowledged.

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