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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 8
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Original Articles

The Use of DMAP as Catalyst in the Baylis-Hillman Reaction Between Methyl Acrylate and Aromatic Aldehydes

Rodrigo Octavio Núcleo de Pesquisas de Produtos Naturais–Universidade Federal do Rio de Janeiro, Centro de Ciências da Saúde, Ilha do Fundão, RJ, Brazil
,
M. A. de Souza Núcleo de Pesquisas de Produtos Naturais–Universidade Federal do Rio de Janeiro, Centro de Ciências da Saúde, Ilha do Fundão, RJ, Brazil
&
Mário Luiz A. A. Vasconcellos Núcleo de Pesquisas de Produtos Naturais–Universidade Federal do Rio de Janeiro, Centro de Ciências da Saúde, Ilha do Fundão, RJ, BrazilCorrespondence[email protected]
Pages 1383-1389 | Received 15 Jun 2002, Published online: 15 Aug 2006
 
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Abstract

We found an efficient methodology for the Baylis-Hillman reaction of p-nitrobenzaldehyde (1), naphtaldehyde (4a), and pyperonal (4b) with methyl acrylate by using 4-dimethylaminopyridine (DMAP) as a catalyst, without solvent, additives, or any sophisticated equipment. A very important temperature effect was observed.

Acknowledgments

National Research Council of Brazil (CNPq), José Bonifácio University Foundation (FUJB-Brazil), and Research Foundation of the Rio de Janeiro (FAPERJ) for a fellowship.

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