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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 8
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Original Articles

Studies on Bromination of Active Methylene by a Mixture of Hydrobromic Acid and Hydrogen Peroxide (or TBHP)

, , &
Pages 1399-1403 | Received 05 Jun 2002, Published online: 15 Aug 2006
 

Abstract

Studies on bromination of active methylene with a mixture of hydrogen peroxide or tert-butylhydroperoxide (TBHP) and hydrobromic acid are discussed. Substituted acetophenones, benzocyclic ketones provide α-bromo-keto compounds in high yields under this reaction condition.

Acknowledgment

A. V. B. and P. D. S. wish to thank CSIR New Delhi for the award of Pool Officership and Senior Research Fellowship, respectively.

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