Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 13
130
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

Electrochemical Sulfonylation of 4-tert-Butylcatechol

, &
Pages 2269-2274 | Received 09 Sep 2002, Published online: 17 Aug 2006
 

Abstract

Electrochemical oxidation of 4-tert-butylcatechol (1) has been studied in the presence of benzenesulfinic acids (2a and 2b) as nucleophiles in aqueous solution, using cyclic voltammetry and controlled-potential coulometry. The results indicate that the quinone derived from 4-tert-butylcatechol (1) participates in Michael addition reaction with 2 of form the corresponding arylsulfonylbenzenediols (3a and 3b). The electrochemical synthesis of 3a and 3b has been successfully performed at carbon rod electrodoes in an undivided cell in good yield and purity.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.