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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 20
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Original Articles

Substitution of the Benzotriazolyl Group in N-(α-Amidoalkyl)benzotriazoles and N-(α-Sulfonamidoalkyl)benzotriazoles with Allylsamarium Bromide

Xiaoxia Wang Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou, P.R. China
,
Jian Li Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou, P.R. China
&
Professor Yongmin Zhang Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou, P.R. China; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P.R. China
Pages 3575-3581 | Received 12 Mar 2003, Published online: 15 Aug 2006
 
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Abstract

The nucleophilic substitution of the benzotriazolyl group in the N-(α-benzotriazol-1-ylalkyl)amides and N-(α-benzotriazol-1-ylalkyl) sulfonamides with allylsamarium bromide was investigated, and the corresponding homoallylamides or homoallylsulfonamides were obtained in good to excellent yields.

Acknowledgment

We are grateful to the National Natural Science Foundation of China (Project No. 20072033) and the Specialized Research Fund for the Doctoral Program of Higher Education of China for financial support.

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