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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 1
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Original Articles

FeCl3 and Yb(OTf)3 Mediated Conversion of Acetates of the Baylis–Hillman Adducts into (Z) and (E) Trisubstituted Alkenes

Palakodety Radha Krishna Discovery Laboratory, Organic Chemistry Division III, Indian Institute of Chemical Technology, Uppal Road, Hyderabad, 500 007, IndiaCorrespondence[email protected]
,
V. Kannan Discovery Laboratory, Organic Chemistry Division III, Indian Institute of Chemical Technology, Uppal Road, Hyderabad, 500 007, India
&
G. V. M. Sharma Discovery Laboratory, Organic Chemistry Division III, Indian Institute of Chemical Technology, Uppal Road, Hyderabad, 500 007, India
Pages 55-64 | Received 30 Jun 2003, Published online: 16 Aug 2006
 
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Abstract

Anhydrous FeCl3 and Yb(OTf)3 are utilised as new reagents for the stereoselective isomerisation of acetates of the Baylis–Hillman adducts to both (Z) and (E) trisubstituted alkenes respectively.

Acknowledgment

V. Kannan acknowledges financial support from the CSIR, New Delhi (India).

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