Abstract
Regio‐ and stereoselective glycosylation of α‐ and β‐octyl glucopyranoside derivatives 2c and 2d, respectively, with glycosyl donor 3 to obtain the corresponding 3‐O‐linked 5c and 2‐O‐linked 4d saccharides, respectively, is described, formation of diglycosylated products 6c and 6d was not observed.