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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 18
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Original Articles

Regioselectivity of Reactions of Nitrogen and Carbon Nucleophiles with Coumarin Derivatives

Perry T. Kaye Department of Chemistry, Rhodes University, Grahamstown, 6140, South AfricaCorrespondence[email protected]
&
Musiliyu A. Musa Department of Chemistry, Rhodes University, Grahamstown, 6140, South Africa
Pages 3409-3417 | Received 02 Jun 2004, Published online: 10 Jan 2011
 
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Abstract

Reaction of various 3‐substituted coumarins with nitrogen and carbon nucleophiles appears to involve, in all cases examined, exclusive, direct substitution at the exocyclic C‐1′ electrophilic center.

Acknowledgments

The authors thank the National Research Foundation (NRF) and Rhodes University for generous financial support.

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