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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 18
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Original Articles

RuCl3 Catalyzed Facile Conversion of Arylalkyl Ketoximes to Amides

Surya Kanta De Department of Medicinal Chemistry and Molecular Pharmacology, Purdue University, West Lafayette, Indiana, 47907, USA
Pages 3431-3434 | Received 27 May 2004, Published online: 12 Jan 2011
 
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Abstract

A variety of aromatic ketoximes undergo Beckmann rearrangement upon treatment with a catalytic amount of RuCl3 in refluxing acetonitrile to furnish the corresponding amides in excellent yield and high selectivity.

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