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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 22
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Original Articles

Convenient Synthesis of Labdane and Drimane Analogues with o‐Quinol Functionality

S. Meenakshi Department of Chemistry, Indian Institute of Technology, Powai, Mumbai, 400 076, India
,
A. Sivaramkrishnan Department of Chemistry, Indian Institute of Technology, Powai, Mumbai, 400 076, India
,
R. Padmakumar Department of Chemistry, Indian Institute of Technology, Powai, Mumbai, 400 076, India
,
Shreeshailkumar B. Hadimani Department of Chemistry, Indian Institute of Technology, Powai, Mumbai, 400 076, India
&
Sujata V. Bhat Department of Chemistry, Indian Institute of Technology, Powai, Mumbai, 400 076, IndiaCorrespondence[email protected]
Pages 4065-4076 | Received 12 Jul 2004, Published online: 10 Jan 2011
 
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Abstract

The Diels–Alder reactions of 4‐carbomethoxy‐o‐benzoquinone with substituted‐1,3‐dienes give high yields of the drimane and labdane analogues containing an orthoquinol moiety.

Acknowledgments

The spectral assistance from R. S. I. C., Bombay and T. I. F. R. Mumbai and sample of citronellol from S. H. Kelkar and Co., Mumbai are gratefully acknowledged. We are thankful to Council of Scientific and Industrial Research for financial assistance.

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