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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 24
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Original Articles

Stereoselective Synthesis of 2,6‐Disubstituted Tetrahydropyridines Via Aza‐Diels‐Alder Reactions

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Pages 4573-4582 | Received 24 Aug 2004, Published online: 10 Jan 2011
 

Abstract

The aza‐Diels‐Alder reactions of (E)‐2‐(phenylthio)‐1,3‐pentadiene (2) with iminium salts gave the 2,6‐disubstituted tetrahydropyridines 38. Factors influencing the stereochemistry and reactivity of these reactions were also studied.

Acknowledgment

Financial support of this work by the National Science Council of the Republic of China is gratefully acknowledged (NSC 91‐2113‐M‐030‐005).

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