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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 1
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Original Articles

Solvent‐Free Microwave Michael Addition Between EMME and Various Nucleophiles

André Loupy Laboratoire des Réactions Sélectives sur Supports, associé au CNRS, UMR 8615‐ICMMO, Université Paris‐Sud, Batiment, Orsay Cédex, France
,
Suk Jin Song College of Science, Kyungsung University, Daeyoen‐dong, Busan, 608‐736, Korea
,
Seong Jin Cho College of Science, Kyungsung University, Daeyoen‐dong, Busan, 608‐736, Korea
,
Dong Kyu Park College of Science, Kyungsung University, Daeyoen‐dong, Busan, 608‐736, Korea
&
Tae Woo Kwon College of Science, Kyungsung University, Daeyoen‐dong, Busan, 608‐736, KoreaCorrespondence[email protected]
Pages 79-87 | Received 18 Aug 2004, Published online: 05 Aug 2006
 
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Abstract

Michael addition reaction between EMME and various O, S, N nucleophiles were investigated in the presence of catalysts such as KF, KOH, or K(OCCH3)3 under solvent‐free conditions either neat or on alumina as solid support. Compared to low reactivity of alcohols (40 to 80% yields according to aliphatic chain), aniline or thiophenol gave good to excellent yields (90–99%).

Acknowledgments

This work was supported by grant from the Kyungsung University research foundation (2003) and Basic Research Program of the Korea Science & Engineering Foundation (KOSEF R05‐2003‐000‐11732‐0).

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