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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 1
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Original Articles

Palladium‐Catalyzed Selective Carbonylation of (E)‐1,2‐Diidoalkenes

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Pages 105-113 | Received 19 Aug 2004, Published online: 05 Aug 2006
 

Abstract

A mild and selective palladium‐catalyzed carbonylation of (E)‐1,2‐diiodoalkenes protocol for the synthesis of (E)‐3‐iodoacrylate esters and maleic diesters has been developed. In the presence of PdCI2, CuCl2, and CO, (E)‐3‐iodoacrylate esters and maleic diesters were obtained selectively in moderate yields. Noteworthysis that a clean inversion of configuration takes place in the palladium‐catalyzed dicarbonylation of (E)‐1,2‐diiodoalkenes procedure.

Acknowledgments

We thank the National Natural Science Foundation of China (No. 20202002), Hunan Province Department of Education (No. 02C211), and Hunan Normal University for financial support.

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