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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 2
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Original Articles

Nitration of Aromatic Compounds by Zn(NO3)2 · 2N2O4 and Its Charcoal‐Supported System

Nasser Iranpoor Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
,
Habib Firouzabadi Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
,
Reza Heydari Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, Iran
&
Morteza Shiri Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, Iran
Pages 263-270 | Received 08 Mar 2004, Published online: 28 Jul 2007
 
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Abstract

Zn(NO3)2 · N2O4 and its charcoal supported system were found to be efficient nitrating agents. Mononitration of aromatic compounds such as benzene, alkyl benzenes, halobenzenes, nitrobenzene, anisol, and the highly selective mono‐, di‐, and trinitration of phenol, and dinitraion of substituted phenols were also performed in the presence of these reagents.

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