Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 11
Submit an article Journal homepage
710
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

Microwave‐Assisted Protection of Phenols as tert‐Butyldimethylsilyl (TBDMS) Ethers Under Solvent‐Free Conditions

Erick L. Bastos Instituto de Química, Universidade de São Paulo, São Paulo, Brazil
,
Luiz F. M. L. Ciscato Instituto de Química, Universidade de São Paulo, São Paulo, Brazil
&
Wilhelm J. Baader Instituto de Química, Universidade de São Paulo, São Paulo, BrazilCorrespondence[email protected]
Pages 1501-1509 | Received 27 Jan 2005, Published online: 17 Dec 2010
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

A facile, time‐saving procedure to protect phenols with tert‐butyldimethylsilyl chloride using imidazole as catalyst under solvent‐free conditions is described. Several phenolic compounds with different substitution patterns can be silylated in high yield with substantially reduced generation of residues, a present goal in organic synthesis.

Acknowledgment

We thank Luiz Fernando da Silva Junior and Dieter Weiß for a critical reading of the manuscript and FAPESP (00/06652‐0, 01/07477‐0) and CAPES for substantial financial support.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.