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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 14
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Original Articles

Bromination of Aromatic Compounds with Potassium Bromide in the Presence of Poly(4‐vinylpyridine)‐Supported Bromate in Nonaqueous Solution

Hassan Tajik Department of Chemistry, Guilan University, Rasht, IranCorrespondence[email protected] [email protected]
,
Farhad Shirini Department of Chemistry, Guilan University, Rasht, Iran
,
Parwin Hassan‐zadeh Department of Chemistry, Guilan University, Rasht, Iran
&
Hassan Rafiee Rashtabadi Department of Chemistry, Guilan University, Rasht, Iran
Pages 1947-1952 | Received 28 Feb 2005, Published online: 16 Aug 2006
 
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Abstract

A simple, efficient, and mild method for selective bromination of activated aromatic compounds using potassium bromide in the presence of poly(4‐vinylpyridine)‐supported bromate in nonaqueous solution is reported. The results obtained revealed excellent to good selectiveity between ortho and para positions of methoxyarenes, anilines, and phenols.

Acknowledgment

We are grateful to the Guilan University Research Council for partial support of this work.

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