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Abstract
Chlorooctakis(octylthio)porphyrazinatoiron(III) (FePzCl) was prepared by the reaction of metal-free porphyrazine with iron(II) acetate and further treatment with HCl solution. The monomeric bisaxial complex FePz(py)2 as well as the bridged complex [FePz(pyz)]n were formed as stable complexes by reacting FePzCl with pyridine or pyrazine, respectively. These complexes were characterized by elemental analysis and spectroscopic methods.
ACKNOWLEDGEMENTS
A. G. is grateful to the Alexander von Humboldt Foundation for a fellowship.