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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 31, 2001 - Issue 6
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Original Articles

SYNTHESES AND CHARACTERIZATION OF THE N,N′-BIS(FERROCENYLMETHYLENE)-ETHYLENEDIAMINE SCHIFF BASE AND ITS TRANSITION METAL COMPLEXES

Hong-yun Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. ChinaCorrespondence[email protected]
,
Jing Lei Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
,
Yi-yun Chen School of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, P. R. China
,
Lin Lin Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
,
Qing-an Wu Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
&
Hong-quan Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
Pages 1053-1061 | Received 21 Aug 2000, Accepted 08 May 2001, Published online: 15 Feb 2007
 
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Abstract

The N,N′-bis(ferrocenylmethylene)ethylenediamine Schiff base was synthesized by condensing ferrocenylaldehyde with ethylenediamine. The complexes of the Schiff base with Zn(II), Co(II), Ni(II) and Fe(III) ions were synthesized. The compositions and properties of the ligand and its complexes were established by elemental analyses, IR, 1H NMR, UV-Vis. spectra and molar conductances.

ACKNOWLEDGMENT

This work supported by the Henan Province Natural Science Foundation of China.

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