Synthesis, Characterization, Spectral Studies, and Antifungal Activity of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) Complexes with Monosodium 4‐(2‐Pyridylazo)resorcinol

Abstract

Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) complexes of the type Na₂[ML₂] · 2H₂O of the title ligand, monosodium 4‐(2‐pyridylazo)resorcinol, NaHL, have been synthesized and characterized by various physico‐chemical (elemental analyses, solubility, electrolytic conductances, and magnetic susceptibility measurements) and spectral (UV‐Visible, IR, ESR, and powder x‐ray diffraction) techniques for structure determination and tested for their antifungal activity. The 1:2 (M:L) complexes showed octahedral geometry around M(II), significant antifungal activity against Curvularia species and Collectotrichum capsici and moderate activity against the fungi Alternaria brassicicola, Alternaria brassicae, Alternaria solanae, Curvularia lunata, Helminthosporium oryzae, Aspergillus niger, Aspergillus flavus, and Fusarium udum.

Keywords:

• Resorcinol
• Azo dyes
• IR spectra
• Antifungal activity

Acknowledgments

One of the authors, Mr. Gajanan Pandey, is grateful to the Council of Scientific and Industrial Research, New Delhi, for financial support. The authors also thank Professor U. P. Singh, Department of Mycology and Plant Pathology, Institute of Agricultural Sciences, Banaras Hindu University, Varanasi, for antifungal activity measurement.