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Original Articles

Synthesis and Characterization of Transition Metal Complexes of α‐Bromo‐ and ω‐Bromoacetoacetanilide Semicarbazones

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Pages 429-442 | Received 06 Sep 2001, Accepted 29 Oct 2003, Published online: 16 Nov 2010
 

Abstract

A series of transition metal complexes of α‐bromo‐ and ω‐bromoacetoacetanilide semicarbazones (L1H2 and L2H2, respectively) were prepared. Characterization of these compounds has been carried out by elemental analyses, infrared, electronic, and 1H NMR spectra and magnetic studies. These studies revealed that the ligands behave as tridentate mono‐ or di‐anions.

Acknowledgments

The authors thank Dr. M. P. Kannan, Head of the Department of Chemistry, Calicut University and the Heads, Regional Sophisticated Instrumentation Center, Central Drug Research Institute, Lucknow; Punjab University, Chandigarh and Regional Sophisticated Instrumentation Center, Indian Institute of Technology, Mumbai, for providing research facilities. Thanks are also due to the University Grants Commission, New Delhi, for financial assistance.

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