52
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Kinetic Evidence of Perborate Oxidation of N‐Methylaniline in Acetic Acid as Borate Assisted Hydrogen Peroxide Oxidation

&
Pages 541-551 | Received 25 Feb 2003, Accepted 27 Nov 2003, Published online: 16 Nov 2010
 

Abstract

Sodium perborate, a true peroxo salt, generates peracetic acid on standing in glacial acetic acid; the oxidations of N‐methylaniline and N,N‐dimethylaniline with fresh solutions of perborate are second order, but the specific oxidation rate of N‐methylaniline increases with [perborate]0. Sodium percarbonate, a dry carrier of hydrogen peroxide, does not generate peracetic acid in glacial acetic acid on aging, and the oxidations of the anilines are clean second order. On dissolution, perborate affords hydrogen peroxide and a borate, and the latter assists the oxidation of N‐methylaniline but not N,N‐dimethylaniline.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 674.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.