52
Views
1
CrossRef citations to date
0
Altmetric
Original Articles

(Z)‐1‐[2‐(Tribenzylstannyl)vinyl]‐1‐cyclooctanol: Synthesis, Characterization, Halodebenzylation, and Crystal Structure

, , , , , & show all
Pages 565-572 | Received 24 Feb 2003, Accepted 03 Dec 2003, Published online: 16 Nov 2010
 

Abstract

The synthesis and properties of (Z)‐1‐[2‐(tribenzylstannyl)vinyl]‐1‐cyclooctanol (1) are described. Compound (1) crystallizes from alcohol in the monoclinic space group P2 1 /c with unit‐cell dimensions a = 9.348(1) Å, b = 26.143(1) Å, c = 10.705(1) Å, β = 95.09(1)°, V = 2605.9(1) Å3, Z = 4, D c = 1.390 g cm−3, μ = 10 cm−1, final R = 0.033 for 3165 observed reflection (|F|2 ≥ 8σ|F|2). The x‐ray diffraction analysis of this compound shows intramolecular coordination of oxygen to the tin atom giving rise to a five‐membered ring in which the metal exhibits a distorted trigonal bipyramidal geometry. Compound (1) by halodebenzylation by Br2 or ICl forms the corresponding (Z)‐1‐[2‐(dibenzylhalostannyl)vinyl]‐1‐cyclooctanol or (Z)‐1‐[2‐(benzyldi‐halostannyl)vinyl]‐1‐cyclooctanol, respectively. All compounds were characterized by elemental analyses, IR, 1H NMR.

Acknowledgment

This project was supported by Dalian University of Technology Innovate Foundation.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 674.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.