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Original Articles

Zn(II) and Pd(II) Complexes of Thiosemicarbazone‐S‐alkyl Esters Derived from 2/3‐Formylpyridine

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Pages 653-665 | Received 10 Apr 2003, Accepted 28 Dec 2003, Published online: 16 Nov 2010
 

Abstract

Representative S‐methyl/ethyl‐4‐H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl2], [Pd(L)Cl2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1H NMR spectra. The multidentate S‐alkyl thiosemicarbazones coordinate as mono‐, bi‐, or tridentate ligands depending on the types of the alkyl moiety and metal ion.

Acknowledgment

This study was supported by the Research Fund of Istanbul University, Project Number 1162/070998.

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