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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 34, 2004 - Issue 6
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Original Articles

Synthesis and Characterization of Water‐Soluble Cu(II) Phthalocyanine Complexes

B. Wang College of Chemistry and Materials Science, Shaanxi Normal University, Xi'An, 710062, P.R. ChinaCorrespondence[email protected]
&
H.‐Zh. Ma College of Chemistry and Materials Science, Shaanxi Normal University, Xi'An, 710062, P.R. China
Pages 1009-1017 | Received 02 Mar 2003, Accepted 19 Feb 2004, Published online: 16 Nov 2010
 
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Abstract

Octa‐carboxylate phthalocyanine Cu(II) complex, CuPc(COONa)8, and their pyridine substitutes CuPc(COONa)8(L)2 (L = Py, 4‐MePy), have been synthesized and characterized on the basis of elemental analyses, molar conductance, IR, 1H NMR, and electronic spectral studies. A structure is proposed in which one Pc molecule is coordinated to a metal ion in a tetradentate fashion.

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