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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 34, 2001 - Issue 5
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Original Articles

EPR OF UV PHOTOLYZED TETRAMETHYLAMMONIUM ACETATE AND TRIBUTYLTIN ACETATE POWDERS

, &
Pages 639-646 | Received 03 May 2000, Accepted 10 Jun 2001, Published online: 15 Feb 2007
 

Abstract

The electron paramagnetic resonance investigation of tetramethylammonium acetate ((CH 3)4 NCH 3 COO) and of tributyltin acetate ((C 4 H 9)3 SnCH 3 COO) powders under UV photolysis were carried out at 120 K. Some damage centers were formed by the UV photolysis which are attributed to ĊH 3 and CO 2 radicals in the first substance and to radical in the second. The g values of the radicals were found to be 2.0642, 2.0305 and 2.0058 respectively. No signals were detected at different doses of the gamma irradiation and UV photolysis for both samples at the room temperature.

Acknowledgments

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