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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 34, 2001 - Issue 5
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Original Articles

VIBRATIONAL SPECTRA AND NORMAL COORDINATE ANALYSIS OF 1,2-BIS(2-FORMYLGLYCINEBENZENESULFENYL) ETHANE Pd(II) DICHLORIDE COMPLEX

Yu Zhang State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing, 210093, Peoples Republic of China
,
Wei Hang State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing, 210093, Peoples Republic of China
,
Shaozhen Zhou State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing, 210093, Peoples Republic of China
,
Chongde Li Department of Chemistry, Nanjing University, Nanjing, 210093, Peoples Republic of China
&
Longgen Zhu State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing, 210093, Peoples Republic of China
Pages 647-663 | Received 01 Aug 1999, Accepted 12 Jun 2001, Published online: 15 Feb 2007
 
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Abstract

The normal coordinate analysis of the title complex, 1,2-bis(2-formylglycinebenzenesulfenyl) ethane Pd(II) dichloride has been carried out by using the Urey-Bradley force field. According to the molecular structure determined by x-ray crystallographic analysis, 182 internal coordinates were established and 112 theoretical vibration frequencies agree well with the observed values with the average difference of 2.53 cm−1 and the maximum deviation of 16.0 cm−1.

Acknowledgments

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