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Original Articles

Effect of Long-Chain Amines on the Extraction of Boron from CaCl2 Brine with CTMP in Petroleum Benzine

, &
Pages 2615-2625 | Received 06 Apr 1998, Published online: 15 Feb 2007
 

Abstract

The effect of TOA (tri-n-octylamine), TOMA (tri-n-octylmethylammonium iodide), DEDA (N,N′-didodecylethylenediamine), DEDMA (N,N′-didodecyl-N,N′-tetramethylethylene-diammonium diiodide), and NDM (N-dodecylmorpholine) upon the solvent extraction of boron from CaCl2 brine with CTMP [2-chloro-4(1,1,3,3,-tetramethylbutyl)-6-methylolphenol] in petroleum benzine has been studied. In order to extract boron effectively and reject other cations such as Ca2+, the extraction of boron with CTMP was investigated in terms of extractant, the concentration of an amine, and solvent polarity. The results show that in the presence of long-chain amines, boron extraction with CTMP in all solvent systems was shifted to a more acidic pH range. Larger extraction, hence distribution, and an increase in selectivity are observed when CTMP is used together with long-chain amines and their ammonium salts in petroleum benzine.

Acknowledgments

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