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Separation Science and Technology Volume 37, 2002 - Issue 14
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Original Articles

SOLVENT EXTRACTION OF LANTHANIDES WITH 1-PHENYL-3-METHYL-4-BENZOYL-5-PYRAZOLONE

V. M. Jordanov Department of Inorganic Chemistry, University of Chemical Technology and Metallurgy, 8, Kliment Okhridski blvd, Sofia, 1756, Bulgaria
,
M. Atanassova Department of Inorganic Chemistry, University of Chemical Technology and Metallurgy, 8, Kliment Okhridski blvd, Sofia, 1756, Bulgaria
&
I. L. Dukov Department of Inorganic Chemistry, University of Chemical Technology and Metallurgy, 8, Kliment Okhridski blvd, Sofia, 1756, BulgariaCorrespondence[email protected]
Pages 3349-3356 | Received 01 Nov 2001, Published online: 20 Aug 2006
 
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Abstract

The solvent extraction behavior of 13 lanthanides has been investigated using 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (HP) as an extractant in aqueous-benzene medium. The composition of the extracted species has been determined as LnP3·HP. The values of the equilibrium constant as well as the separation factors between the adjacent elements have been evaluated.

Acknowledgments

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