Tensile deformation behaviour of high isotactic polypropylenes

Abstract

The tensile flow behaviour and deformation processes during uniaxial loading of high isotactic (high crystallinity) polypropylenes have been investigated at various strain rates. The strain rate sensitivity index indicated that long chain high isotactic (high crystallinity) polypropylene (iPP-L) is relatively less sensitive to strain rate than short chain high isotactic (high crystallinity) polypropylene (iPP-S). Deformation bands formed at low strain contributed to the separation of fibrils/microfibrils, and on subsequent increase in tensile strain, the deformation bands developed into an array of closely spaced crazes that multiplied with an increase in strain and strain rate, and grew inwards. Three fracture morphologies were identified in iPP-L: brittle fracture, crazing - tearing, and brittle fracture with ductile pulling of fibrils/microfibrils (quasi-cleavage). In iPP-S, the predominant mode of failure at all displacement rates was brittle fracture. However, at lower displacement rates, smooth and circular voids associated with nucleating particle were randomly present on the brittle fracture surface of iPP-S. Occasional wedges were also observed on the tensile deformed surface of iPP-S. The deformation processes have been depicted in terms of strain rate - strain deformation diagrams.