Abstract
A new method of preparing iron oxyhydroxide was developed, in which nanoclusters were precipitated from heated aqueous Fe(NO3)3 solution through promotion by CuO. The products of this reaction were characterised. The composition of the products changed with the content of CuO added, but no copper ferrite or solid solution was identified. When the molar ratio of CuO to Fe(NO3)3 was limited to 1∶1, the products were nanoclusters consisting of very small Fe5O7(OH).4H2O ferrihydrite (FH) crystallites. The nanoclusters adsorbed a small amount of Fe(NO3)3, which decreased as the amount of CuO increased when the molar ratio of CuO to Fe(NO3)3 was less than 1∶1. When the molar ratio of the precursors exceeded 1∶1, the amount of Fe(NO3)3 adsorbed onto the FH nanoclusters decreased, and Cu2(OH)3NO3 was found in the precipitate. The experimental results were attributed to the hydrolysis of Fe(NO3)3 being enhanced by CuO acting as a hydrolyte. Saturation behaviour was observed for the addition of CuO. This is a new route to prepare oxide nanoclusters by enhanced hydrolysis.
Acknowledgements
Financial support for this work was provided by the National Science Foundation of China (Grant No. 11074205).