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Plastics, Rubber and Composites
Macromolecular Engineering
Volume 44, 2015 - Issue 4
101
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Research Papers

Mullins effect and its reversibility of compatibilised thermoplastic vulcanisates based on high impact polystyrene/high vinyl polybutadiene rubber blend

, &
Pages 155-161 | Received 01 Feb 2015, Accepted 16 Mar 2015, Published online: 14 May 2015
 

Abstract

Mullins effect under cyclic loading–unloading tests, in uniaxial tension and uniaxial compression, together with its reversibility of high impact polystyrene/high vinyl polybutadiene rubber (HVPBR) thermoplastic vulcanisate (TPV), was investigated systematically, where styrene–butadiene–styrene was used as a compatibiliser. Morphology studies showed that sphere-like HVPBR particles were dispersed evenly in the etched TPV surface with diameters of 4–6 μm. The Mullins effect was evaluated under cyclic loading–unloading tests. Experimental results indicated that an obvious stress softening phenomenon could be observed obviously in the uniaxial loading–unloading cycles in tension and compression tests. The maximum stress during loading–unloading cycle could recover partially; moreover, the maximum stress recovery ability could be remarkably enhanced by increasing heat treatment temperature.

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