Abstract
Zinc–nickel alloy deposition with polyvinyl alcohol and piperonal as bath additives has been investigated. The effects of additive concentration, triethanolamine concentration and other parametric variables on the deposit and solution properties have been studied. Polarisation studies were carried out under different conditions to understand the effect of triethanolamine and the brighteners on the co-deposition. Results indicated that the additives lead to bright alloy deposition containing ∼10% nickel. The deposit produced at the optimum conditions with the additives has a nanograined structure with a γ phase.