Abstract
AISI 316L grade ASTM F138 austenitic stainless steel specimens were low temperature plasma nitrided (LTPN), nitrocarburised (LTPNC) and carburised (LTPC) using different gas mixtures. Different expanded austenite layers formed after each thermochemical treatment. LTPN and LTPCN led to formation of nitrogen supersaturated expanded austenite (γN). After LTPN, a second carbon expanded austenite (γC) layer was formed beneath the nitrogen expanded austenite layer (γN). LTPC led to formation of a carbon supersaturated expanded austenite (γC). Scanning electron microscopy, XRD and microhardness were used to characterise the expanded austenite layers formed on the surface of the specimens. Different mechanisms of formation and growth of the layers are pointed out. XRD results show that the lattice parameter of nitrogen expanded austenite (γN) is higher than that calculated for carbon expanded austenite γC. As a consequence, the lattice expansion Δa/a for the nitrogen rich (γN) phase is higher than the one observed for the (γC) phase and the nitrogen rich expanded austenite layer displays higher hardness than the carbon rich expanded austenite layer. The LTPNC bilayer displays a less steep hardness gradient, indicating that the carbon rich expanded austenite layer can grant mechanical support to the harder nitrogen rich layer.
The authors would like to thank Fundação de Amparo à Pesquisa do Estado de São Paulo for financial support to Project PRONEX-Temático (No. 03/10157-2).