Study on behaviour and mechanism of Cu²⁺ ion release from Cu bearing antibacterial stainless steel

Abstract

Cu bearing stainless steels (Cu SS) possess antibacterial ability due to the release of Cu²⁺ ions. However, the release mechanism of Cu²⁺ ions from the steel is still unclear. Therefore, the passive film on the surface of Cu SS, the reason of Cu²⁺ ions release and chemical reactions during Cu²⁺ ions release were studied by means of X-ray photoelectron spectroscopy analysis and electrochemical measurements. According to the results, the release mechanism of Cu²⁺ ions release from the Cu SS can be proposed as following: Cu rich phases in the steel promote the segregation of surrounding C and Cr to form Cr₂₃C₆, which affects the integrity and stability of the Cr₂O₃ passive film surrounding themselves. Thus, the Cu rich phases are easy to be attacked as weak points in the corrosive media, which led to serial chemical reactions occurring while promoting the releases of Cu²⁺ ions and playing the antibacterial role.

Keywords:

• Cu bearing stainless steel
• Antibacterial
• Cu ions
• Release mechanism of Cu²⁺ ions

Acknowledgements

This work was financially supported by the National Natural Science Foundation (nos. 51171186 and 81301329), the National Basic Research Program of China (no. 2012CB619101), Shenyang National Lab for Materials Science, Foundation of Jiangsu Collaborative Innovation Center of Biomedical Functional Materials and the UK Royal Academy of Engineering (RAEng. 1213RECI052).