365
Views
6
CrossRef citations to date
0
Altmetric
Environmental Analysis

Determination of Ultra-Trace Platinum, Palladium, Ruthenium, Rhodium, and Iridium in Rocks and Minerals by Inductively Coupled–Plasma Mass Spectrometry Following Nickel Sulfide Fire Assay Preconcentration and Open Mixed Acid Digestion

, &
Pages 1699-1710 | Received 19 Oct 2018, Accepted 04 Jan 2019, Published online: 24 Apr 2019

References

  • Brandon, A. D., R. J. Walker, J. W. Morgan, M. D. Norman, and H. M. Prichard. 1998. Coupled 186Os and 187Os evidence for core–mantle interaction. Science 280 (5369):1570–1573. doi:10.1126/science.280.5369.1570.
  • Date, A. R., A. E. Davis, and Y. Y. Cheung. 1987. The potential of fire assay and inductively coupled plasma source mass spectrometry for the determination of platium group elements in geological materials. The Analyst 112 (9):1217–1222. doi:10.1039/an9871201217.
  • Eskina, V. V., O. A. Dalnova, D. G. Filatova, V. B. Baranovskaya, and Y. A. Karpov. 2016. Sepration and preconcentration of platinum-group metals from spent autocatalysts solutions using a hetero-polymeric S, N-containing sorbent and determination by high-resolution continuum source graphite furnace atomic adsorption spectrometry. Talanta 159:103–110. doi:10.1016/j.talanta.2016.06.003.
  • Hoffman, E. L., A. J. Naldrett, J. C. Van Loon, R. G. V. Hancock, and A. Manson. 1978. The determination of all the platinum-group elements and gold in rocks and ore by neutron activation analysis after preconcentration by a nickel sulfide fire assay technique on large samples. Analytica Chimica Acta 102:157–166. doi:10.1016/S0003-2670(01)93469-5.
  • Jackson, S. E., B. J. Fryer, W. Gosse, D. C. Healey, H. P. Longerich, and D. F. Strong. 1990. Determination of the precious metals in geological materials by inductively coupled plasma-mass spectrometry (ICP-MS) with nickel sulphide fire-assay collection and tellurium coprecipitation. Chemical Geology 83 (1-2):119–132. doi:10.1016/0009-2541(90)90144-V.
  • Jarvis, K. E., J. G. Williams, S. J. Parry, and E. Bertalan. 1995. Quantitative determination of platinum-group elements and gold using nis fire assay with laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Chemical Geology 124 (1-2):37–46. doi:10.1016/0009-2541(95)00022-E.
  • Marguí, E., I. Queralt, and M. Hidalgo. 2013. Determination of platinum group metal catalyst residues in active pharmaceutical ingredients by means of total reflection X-ray spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy 86:50–54. doi:10.1016/j.sab.2013.05.024.
  • McDonald, I., R. J. Hart, and M. Tredoux. 1994. Determination of the platinum-group elements in South african kimberlites by nickel sulphide fire-assay and neutron activation analysis. Analytica Chimica Acta 289 (2):237–247. doi:10.1016/0003-2670(94)80108-8.
  • Oguri, K., G. Shimoda, and Y. Tatsumi. 1999. Quantitative determination of gold and platinum-group elements in geological samples using improved nis fire-assay and tellium coprecipitation with inductively coupled plasma-mass spectrometry (ICP-MS). Chemical Geology 157 (3-4):189–197. doi:10.1016/S0009-2541(98)00205-8.
  • Pattou, L., J. P. Lorand, and M. Gros. 1996. Non-chondritic platinum group element ratios in the earth’s mantle. Nature 379 (6567):712–715. doi:10.1038/379712a0.
  • Reddi, G. S., C. R. M. Rao, T. A. S. Rao, S. V. Lakshmi, R. K. Prabhu, and T. R. Mahalingam. 1994. Nickel suiphide fire assay-ICPMS method for the determination of platinum-group elements: a detailed study on the recovery and losses at different stages. Fresenius' Journal of Analytical Chemistry 348(5-6):350–352. doi:10.1007/BF00323133.
  • Resano, M., E. García-Ruiz, K. S. McIntosh, J. Hinrichs, I. Deconinck, and F. Vanhaecke. 2006. Comparison of the solid sampling techniques laser ablation-ICP-MS, glow discharge-MS and spark-OES for the determination of platinum group metals in Pb buttons obtained by fire assay of platiniferous ores. Journal of Analytical Atomic Spectrometry 21 (9):899–909. doi:10.1039/B603270B.
  • Snow, J. E., and G. Schmidt. 1998. Constraints on earth accretion deduced from noble metals in the oceanic mantle. Nature 391 (6663):166–169. doi:10.1038/34396.
  • Shazali, I., Van, L. D. T., and R. Gijbels. 1987. Determination of precious metals in ores and rocks by thermal neutron activation/γ-spectrometry after preconcentration by nickel sulfide fire assay and coprecipitation with tellurium. Analyca Chimica Acta 196:49–58. doi:10.1016/S0003-2670(00)83069-X.
  • Sun, Y. L., X. Y. Guan, and A. D. Du. 1998. Determination of platinum group elements by inductively coupled plasma-mass spectrometry combined with nickel sulfide fire assay and tellurium coprecipitation. Spectrochimica Acta Part B: Atomic Spectroscopy 53 (10):1463–1467. doi:10.1016/S0584-8547(98)00167-0.
  • Sun, Y. L., and M. Sun. 2005. Nickel sulfide fire assay improved for pre-concentration of platinum group elements in geological samples: a practical means of ultra-trace analysis combined with inductively coupled plasma-mass spectrometry. The Analyst 130 (5):664–669. doi:10.1039/b416844e.
  • Yi, Y. V., and A. Masuda. 1996. Simultaneous determination of ruthenium, palladium, iridium and platinum at ultratrace levels by isotope dilution inductively coupled plasma mass spectrometry in geological samples. Analytical Chemistry 68 (8):1444–1450. doi:10.1021/ac951121y.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.