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Spectrophotometry

Determination of Free Glycerol in Biodiesel by Molecularly Imprinted Polymer – Based Solid-Phase Extraction (SPE) Using an Enzymatic Spectrophotometric Assay

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Pages 1654-1667 | Received 05 May 2020, Accepted 04 Sep 2020, Published online: 16 Sep 2020

References

  • Andrade, D. F., J. L. Mazzei, and L. A. D’Avila. 2011. Separation of acylglycerols from biodiesel by high performance liquid chromatography and solid-phase extraction. Revista Virtual de Quimica 3 (6):452–66. doi:10.5935/1984-6835.20110050.
  • ASTM International. 2017. Standard test method for determination of total monoglycerides, total diglycerides, total triglycerides, and free and total glycerin in B-100 biodiesel methyl esters by gas chromatography. West Conshohocken, PA: ASTM International. www.astm.org.
  • Beatriz, A., Y. J. K. Araújo, and D. P. De Lima. 2011. Glycerol: A brief history and application in stereoselective synthesis. Química Nova 34 (2):306–19. doi:10.1590/S0100-40422011000200025.
  • Casarin, J., A. C. Gonçalves Junior, M. G. Segatelli, and C. R. T. Tarley. 2018. Insight into the performance of molecularly imprinted poly(methacrylic acid) and polyvinylimidazole for extraction of imazethapyr in aqueous medium. Chemical Engineering Journal 343:583–96. doi:10.1016/j.cej.2018.03.030.
  • Corazza, M. Z., E. S. Ribeiro, M. G. Segatelli, and C. R. T. Tarley. 2014. Study of cross-linked poly(methacrylic acid) and polyvinylimidazole as selective adsorbents for on-line preconcentration and redox speciation of chromium with flame atomic absorption spectrometry determination. Microchemical Journal 117:18–26. doi:10.1016/j.microc.2014.05.016.
  • van Grinsven, B., K. Betlem, T. J. Cleij, C. E. Banks, and M. Peeters. 2017. Evaluating the potential of thermal read-out techniques combined with molecularly imprinted polymers for the sensing of low-weight organic molecules. Journal of Molecular Recognition 30 (1):e2563. doi:10.1002/jmr.2563.
  • Gutiérrez-Climente, R., A. Gómez-Caballero, M. Halhalli, B. Sellergren, M. A. Goicolea, and R. J. Barrio. 2016. Iniferter-mediated grafting of molecularly imprinted polymers on porous silica beads for the enantiomeric resolution of drugs. Journal of Molecular Recognition: JMR 29 (3):106–14. doi:10.1002/jmr.2443.
  • Honório, G. G., J. N. da Cunha, K. L. dos Santos Castro Assis, P. F. de Aguiar, D. F. de Andrade, C. G. de Souza, L. A. d’Avila, B. S. Archanjo, C. A. Achete, R. N. C. Pradelle, et al. 2019. Free glycerol determination in biodiesel samples using palladium nanoparticles modified glassy carbon electrode associated with solid phase extraction. Journal of Solid State Electrochemistry 23 (11):3057–66. doi:10.1007/s10008-019-04387-2.
  • Huang, B., L. Xiao, H. Dong, X. Zhang, W. Gan, S. Mahboob, K. A. Al-Ghanim, Q. Yuan, and Y. Li. 2017. Electrochemical sensing platform based on molecularly imprinted polymer decorated n,s co-doped activated graphene for ultrasensitive and selective determination of cyclophosphamide. Talanta 164:601–7. doi:10.1016/j.talanta.2016.11.009.
  • Knothe, G. 2002. Structure indices in FA chemistry. How relevant is the iodine value? Journal of the American Oil Chemists' Society 79 (9):847–54. doi:10.1007/s11746-002-0569-4.
  • Lobo, I. P., S. L. C. Ferreira, and R. S. Da Cruz. 2009. Biodiesel: Quality parameters and analytical methods. Química Nova 32 (6):1596–608. doi:10.1590/S0100-40422009000600044.
  • Long, G. L., and J. D. Winefordner. 1983. Limit of detection: A closer look at the IUPAC definition. Analytical Chemistry 55 (07):712A–24A. doi:10.1021/ac00258a724.
  • Luetkmeyer, T., R. M. dos Santos, A. B. da Silva, R. S. Amado, E. de Castro Vieira, and E. D'Elia. 2010. Analysis of free and total glycerol in biodiesel using an electrochemical assay based on a two-enzyme oxygen-electrode system. Electroanalysis 22 (9):995–9. doi:10.1002/elan.200900428.
  • Mercer, E. J., and F. Halaweish. 2011. Determination of free glycerol in biodiesel via solid-phase extraction and spectrophotometric analysis. Journal of the American Oil Chemists' Society 88 (5):655–9. doi:10.1007/s11746-010-1707-6.
  • Mesquita, P. D. L., R. J. de Cassia Franco Afonso, S. F. de Aquino, and G. D. S. Leite. 2013. Validation of a liquid chromatography methodology for the analysis of seven volatile fatty acids intermediates of anaerobic digestion. Engenharia Sanitaria e Ambiental 18 (4):295–302. doi:10.1590/S1413-41522013000400001.
  • Monteiro, M. R., A. R. P. Ambrozin, L. M. Lião, and A. G. Ferreira. 2008. Critical review on analytical methods for biodiesel characterization. Talanta 77 (2):593–605. doi:10.1016/j.talanta.2008.07.001.
  • Muniz, R. O., S. B. Martins, G. G. Honório, J. N. da Cunha, C. G. de Souza, D. F. de Andrade, R. N. C. Pradelle, F. Turkovics, R. S. Neto, L. A. d'Avila, et al. 2019. Total glycerol analysis in biodiesel samples using solid phase extraction coupled with enzymatic-spectrophotometric determination. Analytical Methods 11 (6):767–73. doi:10.1039/C8AY02736F.
  • National Institute of Metrology Quality and Technology. 2016. Guidance on validating chemical testing methods.
  • Prados, C. P., D. R. Rezende, L. R. Batista, M. I. R. Alves, and N. R. Antoniosi Filho. 2012. Simultaneous gas chromatographic analysis of total esters, mono-, di- and triacylglycerides and free and total glycerol in methyl or ethyl biodiesel. Fuel 96:476–81. doi:10.1016/j.fuel.2011.11.060.
  • Rao, R. N., P. K. Maurya, and S. Khalid. 2011. Development of a molecularly imprinted polymer for selective extraction followed by liquid chromatographic determination of sitagliptin in rat plasma and urine. Talanta 85 (2):950–7. doi:10.1016/j.talanta.2011.05.002.
  • Rego, E. C. P. 2013. Internal publication of method validation course. National Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO).
  • Ribeiro, M. S., and F. R. P. Rocha. 2013. A Single-phase spectrophotometric procedure for in situ analysis of free glycerol in biodiesel. Microchemical Journal 106:23–6. doi:10.1016/j.microc.2012.04.011.
  • Santos, A. P. B., and A. C. Pinto. 2009. Biodiesel: A clean fuel alternative. Química Nova Escola 31 (1):58–62.
  • Santos, W., J. R. de, P. R. Lima, C. R. T. Tarley, N. F. Höehr, and L. T. Kubota. 2009. Synthesis and application of a peroxidase-like molecularly imprinted polymer based on hemin for selective determination of serotonin in blood serum. Analytica Chimica Acta 631 (2):170–6. doi:10.1016/j.aca.2008.10.034.
  • Shishov, A., I. Trufanov, D. Nechaeva, and A. Bulatov. 2019. A reversed-phase air-assisted dispersive liquid-liquid microextraction coupled with colorimetric paper-based analytical device for the determination of glycerol, calcium and magnesium in biodiesel samples. Microchemical Journal 150:104134. doi:10.1016/j.microc.2019.104134.
  • Silva, S. G., Á. Morales-Rubio, M. De La Guardia, and F. R. P. Rocha. 2011. Sequential spectrofluorimetric determination of free and total glycerol in biodiesel in a multicommuted flow system. Analytical and Bioanalytical Chemistry 401 (1):365–71. doi:10.1007/s00216-011-5058-4.
  • Silva, S. G., and F. R. P. Rocha. 2010. A flow injection procedure based on solenoid micro-pumps for spectrophotometric determination of free glycerol in biodiesel. Talanta 83 (2):559–64. doi:10.1016/j.talanta.2010.09.061.
  • Tarley, C. R. T., M. D. P. T. Sotomayor, and L. T. Kubota. 2005. Biomimetic polymers in analytical chemistry. Part 1: Preparation and applications of MIP (“Molecularly Imprinted Polymers”) in extraction and separation techniques. Química Nova 28 (6):1076–86. doi:10.1590/S0100-40422005000600024.
  • Zeng, Y., Y. Zhou, L. Kong, T. Zhou, and G. Shi. 2013. A novel composite of SiO2-coated graphene oxide and molecularly imprinted polymers for electrochemical sensing dopamine. Biosensors & Bioelectronics 45 (1):25–33. doi:10.1016/j.bios.2013.01.036.

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