417
Views
90
CrossRef citations to date
0
Altmetric
Original Articles

Low temperature oxidation of methane: the influence of nitrogen oxides

, &
Pages 31-71 | Received 17 Nov 1998, Accepted 16 Apr 1999, Published online: 24 Oct 2007

References

  • Alzueta , M. U. , Muro , J. , Bilbao , R. , and Glarborg , P. Oxidation of Dimethyl Ether and Its Interaction with Nitrogen Oxides. Israel J. Chem. , 39 , ( 1999 ), 73 – 86 .
  • Amano , T. , and Dryer , F. L. ( 1998 ): Effect of Dimethyl Ether. NOx and Ethane on CH4 Oxidation: High Pressure, Intermediate Temperature Experiments and Modelling. Twenty-Seventh Symposium (International) on Combustion , pp. 397 – 404 . The Combustion Institute, Pittsburgh . PA .
  • Ashmore , P. G. , and Preston , K.F. , Sensitized Ignitions of Methane and Oxygen. Combust. Flame , 11 , ( 1967 ), 125 – 134 .
  • Atkinson , R. , Baulch , D. L. , Cox , R. A. , Hampson , Jr., R. F., Kerr , J. A. , and Troe , J. ( 1992 ). Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry. Supplement IV. J. Phys. Chem. Ref. Data , 21 , 1125 – 1568 .
  • Baulch , D. L. , Cobos , C. J. , Cox , R. A. , Esser , C. , Frank , P. , Just , T. , Kerr , J. A. , Pilling , M. J. , Troe , J. , Walker , R. W. , and Wamatz , J. ( 1992 ). Evaluated Kinetic Data for Combustion Modelling. J. Phys. Chem. Ref. Data , 21 , 411 – 429 .
  • Baulch , D. L. , Cobos , C. J. , Cox , R. A. , Frank , P. , Hayman , G. , Just , T. , Kerr , J. A. , Murrells , T. , Pilling , M. J. , Troe , J. , Walker , R. W. , and Warnatz , J. ( 1994 ). Evaluated Kinetic Data for Combustion Modelling. Supplement I. J. Phys. Chem. Ref. Data , 23 , 847 – 1033 .
  • Bendtsen , A. B. , Glarborg , P. , and Dam-Johansen , K. Visualization Methods in Analysis of Detailed Chemical Kinetics Modelling. , ( 1999 ), Submitted for publication.
  • Bowman , C. T. , Hanson , R. K. , Davidson , D. F. , Gardiner , W. C. , Lissianski , V. , Smith , G. P. , Golden , D. M. , Frenklach , M. , and Goldenberg , M. ( 1996 ). GRI-MECH 2.11. , Gas Research Institute, http://www.me.berkeley.edu/gri_mech/.
  • Bromly , J. H. , Barnes , F. J. , Mandyczewsky , R. , Edwards , T. , and Haynes , B. S. ( 1992 ). An Experimental Investigation of the Mutually Sensitised Oxidation of Nitric Oxide and n-butane. Twenty-Fourth Symposium (International) on Combustion , pp. 899 – 907 , The Combustion Institute, Pittsburgh , PA .
  • Bromly , J. H. , Barnes , F. J. , Nelson , P. F. , and Haynes , B. S. ( 1995 ). Kinetics and Modeling of the H2O2-NOx System. Int. J. Chem. Kin. , 27 , 1165 – 1178 .
  • Bromly , J. H. , Bames , F. J. , Muris , S. , You , X. , and Haynes , B. S. ( 1996 ). Kinetic and Thermodynamic Sensitivity Analysis of the NO Sensitised Oxidation of Methane. Combust. Sci. Techn. , 115 , 259 – 296 .
  • Burcat , A. , and McBride , B. Ideal Gas Thermodynamic Data for Combustion and Air Pollution Use. , Israel Institute of Technology, Haifa , Israel ( 1993 ) , TAE 697. Technion, .
  • Dabora , E. K. Effect of NO2 on the Ignition Delay of CH4-Air Mixtures. Combust. Flame , 24 , ( 1975 ), 181 – 184 .
  • Deters , R. , Otting , M. , Wagner , H. Gg. , Temps , F. , Laszlo , B. , Dobe , S. , and Berces , T. A Direct Investigation of the Reaction CH3 + OH. Overall Rate Constant and CH2 Formation at T = 298 K. Ber.Bunsenges. Phys. Chem. , 102 , ( 1998 ), 58 – 72 .
  • de Wit , J. , Kuril , B. , Nielsen , M. , and Kristensen , P. G. Emission and Reduction of Organic Flue Gas Components from Lean-bum Gas Engines. 1998 International Gas Research Conference , San Diego, USA , California , ( 1998 ). .
  • Dorko , E. A. , Bass , D. M. , and Crossley , R. W. ( 1975 ). Shock Tube Investigation of Ignition in Methane-Oxygen-Nitrogen Dioxide-Argon Mixtures , Combust. Flame. , 24 , 173 – 180 .
  • Doughty , A. , Bames , F. J. , Bromly , J. H. , and Haynes , B. S. , ( 1997 ). The Mutually Sensitised Oxidation of Ethylene and NO: An Experimental and Kinetic Modeling Study. Twenty-Sixth Symposium (International) on Combustion , pp. 589 – 596 , The Combustion Institute, Pittsburgh , PA .
  • Galactics Industries Galactics Spectral Database. , Galactic Industries Corp. ( 1998 ): http://www.galactic.com/galactic/_gala/data.htm.
  • Glaenzer , K. , and Troe , J. ( 1972 ). Thermal Fall-Off Reactions of Nitro-Compounds I: Dissociation of Nitromethane. Helv. Chim. Acta , 55 , 2884 – 2893 .
  • Glarborg , P. , Dam-Johansen , K. , Miller , J. A. , Kee , R. J. , and Coltrin , M. E. ( 1994 ). Modeling the Thermal DENOx Process in Flow Reactors. Surface Effects and Nitrous Oxide Formation. Int. J. Chem. Kin. , 26 , 421 – 436 .
  • Glarborg , P. , Kubel , D. , Kristensen , P. G. , Hansen , J. , and Dam-Johansen , K. Interactions of CO, NOx, and H20 under Post-Flame Conditions. Combust. Sci. Techn. , 110 – 111 , ( 1995 ): 461 – 485 .
  • Glarborg , P. , Alzueta , M. U. , Dam-Johansen , K. , and Miller , J. A. Kinetic Modeling of Hydrocarbon/Nitric Oxide Interactions in a Flow Reactor. Combust. Flame. , 115 , ( 1998 ): 1 – 27 .
  • Glarborg , P. , Bendtsen , A. B. , and Miller , J. A. Nitromethane Dissociation. Implications for the CH3 + NO2 Reaction. Int. J, Chem. Kin. , ( 1999 ). in press.
  • Hjuler , K. , Glarborg , P. , and Dam-Johansen , K. Mutually Promoted Thermal Oxidation of Nitric Oxide and Organic Compounds. Ind. Engn. Chem. Res. , 34 , ( 1995 ). 1882 – 1888 .
  • Hulgaard , T. , and Dam-Johansen , K. , Homogeneous Nitrous Oxide Formation and Destruction under Combustion Conditions. AIChE J. , 39 , ( 1993 ), 1342 – 1354 .
  • Humpfer , R. , Oser , H. , Grotheer , H. -H., and Just , T. The Reaction System CH3 + OH at Intermediate Temperatures. Appearance of a New Product Channel. Twenty-Fifth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , PA ( 1994 ). , pp. 721 – 731 ,
  • Hunter , T. B. , Wang , H. , Litzinger , T. A. , Frenklach , M. ( 1994 ). The Oxidation of Methane at Elevated Pressures: Experiments and Modeling. Combust. Flame , 97 , 201 – 224 .
  • Kee , R. J. , Rupley , F. M. , and Miller , J. A. CHEMK1N-II: A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics , Sandia National Laboratories, Livermore, USA , CA ( 1989 ). , SAND 89-8009 B. .
  • Kristensen , P. G. Nitrogen Burnout Chemistry. , PhD thesis. Technical University of Denmark, Lyngby , Denmark ( 1995 ). , Dept.of Chem. Eng., .
  • Kristensen , P. G. , Glarborg , P. , and Dam-Johansen , K. Nitrogen Chemistry during Burnout in Fuel-Staged Combustion. Combust. Flame , 107 , ( 1996 ). 211 – 222 .
  • Kristensen , P. G. , Karll , B. , Bendtsen , A. B. , Glarborg , P. , and Dam-Johansen , K. Exhaust Oxidation of Unbumt Hydrocarbons from Lean-Bum Natural Gas Engines. , ( 1999 ), Submitted for publication.
  • Lightfoot , P. D. , Roussel , P. , Caralp , F. , and Lesclaux , R. Flash Photolysis Study of the CH3O2+CH3O2 and CH3O2+HO2 Reactions between 600 and 719 K: Unimolecular Decomposition of Methylhydroperoxide. J. Chem. Soc. Faraday Trans. , 87 , ( 1991 ), 3213 – 3220 .
  • Lightfoot , P. D. , Cox , R. A. , Crowley , J. N. , Destriau , M. , Hayman , G. D. , Jenkin , M. E. , Moortgat , G. K. , Zabel , F. , Organic Peroxy Radicals: Kinetics, Spectroscopy and Tropospheric Chemistry. Atmos. Environ. , 26 A, ( 1992 ). 1806 – 1961 .
  • Lutz , A. E. , Kee , R. J. , and Miller , J. A. SENKIN: A Fortran program for predicting homogenous gas phase chemical kinetics with sensitivity analysis. , Sandia National Laboratories, Livermore, USA , CA ( 1988 ) SAND 87-8248.
  • Miller , J. A. , and Bowman , C. T. Mechanism and Modeling of Nitrogen Chemistry in Combustion. Prog. Energy Combust. Sci. , 15 , ( 1989 ), 287 – 338 .
  • Nelson , P. F. , and Haynes , B. S. Hydrocarbon-NOx Interactions at Low Temperatures. I. Conversion of NO to NO2 Promoted by Propane and the Formation of HNCO. Twenty-Fifth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , PA ( 1994 ). .pp. 1003 – 1010 ,
  • Nonish , R. G. W. , and Wallace , J. The Reaction of Methane and Oxygen Sensitized by Nitrogen Peroxide. Part I - Thermal Ignition. Proc. Roy. Soc. , A145 , ( 1934 ). 307 – 321 .
  • Pereira , R. D. A. , Baulch , D. L. , Pilling , M. J. , Robertson , S. H. , and Zeng , G. Temperature and Pressure Dependence of the Multichannel Rate Coefficients for the CH3 + OH System. J. Phys. Chem. A , 101 , ( 1997 ), 9681 – 9693 .
  • Prabhu , S. K. , Bhat , R. K. , Miller , D. L. , and Cemansky , N. P. I-Pentene Oxidation and Its Interaction with Nitric Oxide in the Low and Negative Temperature Coefficient Regions. Combust. Flame , 104 , ( 1996 ), 377 – 390 .
  • Rota , R. , Morbidelli , M. , and Carra , S. Combustion Kinetics of Light Hydrocarbons in the Presence of Nitrogen Oxide. Ind. Eng. Chem. Res. , 37 , ( 1998 ), 4241 – 4252 .
  • Slack , M. W. , and Grillo , A. R. Shock Tube Investigation of Methane-Oxygen Ignition Sensitized by NO2. Combust. Flame , 40 , ( 1981 ), 155 – 172 .
  • Slagle , I. R. , and Gutman , D. Kinetics of Polyatomic Free Radicals Produced by Laser Photolysis. 5. Study of the Equilibrium CH3+O2 = CH3O2 between 421 and 538°C J. Am. Chem. Soc. , 107 , ( 1985 ). 5342 – 5347 ,
  • Slemr , F. , and Warneck , P. Kinetics of the Reaction of Atomic Hydrogen with Methyl Hydroperoxide. Int. J. Chem. Kin. , 9 , ( 1977 ), 267 .
  • Smith , J. , Phillips , J. , Graham , A. , Steele , R. , Redondo , A. , and Coons , J. ( 1997 ). Homogeneous Chemistry in Lean-Bum Exhaust Mixtures. J. Phys. Chem. A , 102 , 9157 – 9162 .
  • Tsang W. , and Hampson , R. F. Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds. J. Phys. Chem. Ref. Data , 15 , ( 1986 ), 1087 – 1279 .
  • Vaghjiani G , L. , and Ravishankara , A. R. The Rate Coefficient for the Reaction of O(3p) with CH3OOH at 297 K. Int. J. Chem. Kin. , 22 , ( 1990 ), 351 .
  • Vajda , S. , Valko , P. , and Turányi , T. ( 1985 ). Principal Component Analysis of Kinetic Models. Int. J. Chem. Kinet. , 17 , ( 1990 ) 55 – 81 .
  • Villalta , P. W. , Huey , L. G. , and Howard , C. J. A Temperature-Dependent Kinetics Study of the CH3O2 + NO Reaction Using Chemical Ionization Mass Spectrometry. J. Phys. Chem. , 99 , ( 1995 ). 12829 – 12834 .
  • Yu , C.-L. , Wang , H. , and Frenklach , M. ( 1995 ). Chemical Kinetics of Methyl Oxidation by Molecular Oxygen. J. Phys. Chem. , 99 , 14377 – 14387 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.