115
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

THERMAL DECOMPOSITONS OF 1,1,1-TRIFLUOROETHANE AND PENTAFLUOROETHANE IN A TURBULENT FLOW REACTOR

, , , &
Pages 1417-1432 | Received 24 Apr 2006, Accepted 28 Nov 2006, Published online: 01 Jun 2007

REFERENCES

  • Aviyente , V. and Inel , Y. ( 1989 ) Analysis of the kinetics of the thermal decomposition of pentafluoroethane . Can. J. Chem. , 68 , 1332 – 1337 .
  • Buravtsev , N.N. , Grigor'ev , A.S. , and Kolbanovskii, Yu.A. ( 1989 ) Kinetics and mechanism of pyrolysis of hexafluoropropylene . Kinetika i Kataliz , 30 , 21 – 30 .
  • Burgess , D.R.F. , Jr., Zachariah , M. , Tsang , W. , and Westmoreland , P.R. (1996) Thermochemical and chemical kinetic data for fluorinated hydrocarbons. Prog. Energy Combust. Sci. , 21, 453–529.
  • Cadman , P. , Day , M. , and Trotman-Dickenson , A.F. ( 1971 ) Static and Shock tube pyrolyses of alkyl fluorides. Part III. The hermal decomposition of 1-chloro-2-fluoroethane, 1,1-difluoroethane, and 1,1,1-trifluoroethane . J. Chem. Soc. A , 1356 – 1360 .
  • Curtiss , L.A. , Raghavachari , K. , Trucks , G.W. , and Pople , J.A. ( 1991 ) Gaussian-2 theory for molecular energies of first- and second-row compounds . J. Chem. Phys. , 94 , 7221 – 7230 .
  • Curtiss , L.A. , Raghavachari , K. , and Pople , J.A. ( 1993 ) Gaussian-2 theory using reduced M⊘ller-plesset orders . J. Chem. Phys. , 98 , 1293 – 1298 .
  • Frisch , M.J. , Trucks , G.W. , Schlegel , H.B. , Scuseria , G.E. , Robb , M.A. , Cheeseman , J.R. , Zakrzewski , V.G. , Montgomery , J.A. , Jr. , Stratmann , R.E. , Burant , J.C. , Dapprich , S. , Millam , J.M. , Daniels , A.D. , Kudin , K.N. , Strain , M.C. , Farkas , O. , Tomasi , J. , Barone , V. , Cossi , M. , Cammi , R. , Mennucci , B. , Pomelli , C. , Adamo , C. , Clifford , S. , Ochterski , J. , Petersson , G.A. , Ayala , P.Y. , Cui , Q. , Morokuma , K. , Rega , N. , Salvador , P. , Dannenberg , J.J. , Malick , D.K. , Rabuck , A.D. , Raghavachari , K. , Foresman , J.B. , Cioslowski , J. , Ortiz , J.V. , Baboul , A.G. , Stefanov , B.B. , Liu , G. , Liashenko , A. , Piskorz , P. , Komaromi , I. , Gomperts , R. , Martin , R.L. , Fox , D.J. , Keith , T. , Al-Laham , M.A. , Peng , C.Y. , Nanayakkara , A. , Challacombe , M. , Gill , P.M.W. , Johnson , B. , Chen , W. , Wong , M.W. , Andres , J.L. , Gonzalez , C. , Head-Gordon , M. , Replogle , E.S. , and Pople , J.A. ( 2002 ) Gaussian 98 , Revision A.11.3 , Gaussian, Inc. , Pittsburgh .
  • Harrison , G.C. ( 1995 ) Halon replacement in aircraft and industrial applications . In Miziolek , A.W. and Tsang , W. (Eds.) Halon Replacements , American Chemical Society , Washington , DC , Chap. 8 , pp. 74 – 84 .
  • Linteris , G.T. , Burgess , D.R. , Jr., Babushok , V. , Zachariah , M. , Tsang , W. , and Westmoreland , P.R. ( 1998 ) Inhibition of premixed methane-air flames by fluoroethanes and fluoropropanes . Combust. Flame , 113 , 164 – 180 .
  • Molina , M.J. and Rowland , F.S. ( 1974 ) Stratospheric sink for chlorofluoromethanes: Chlorine atom-catalysed destruction of ozone . Nature , 249 , 810 – 812 .
  • Robin , M.L. ( 1995 ) Halogenated Fire suppression agents . In Miziolek , A.W. and Tsang , W. (Eds.) Halon Replacements , American Chemical Society , Washington , DC , Chap.9 , pp. 85 – 98 .
  • Saso , Y. , Zhu , D.L. , Wang , H. , Law , C.K. , and Saito , N. ( 1998 ) Laminar burning velocities of trifluoromethane-methane mixtures: Experiment and numerical simulation . Combust. Flame , 114 , 457 – 468 .
  • Sianesi , D. , Nelli , G. , and Fontanelli , R. ( 1968 ) Aspetti cinetici e di meccanismo nelle reazioni di deidroalogenazione termica di etani fluorurati e clorofluorurati . Chim. Ind. (Milan) , 50 , 619 – 627 .
  • Tsang , W. , Burgess , D.R. F, Jr., and Babushok , V. ( 1998 ) On the incinerability of highly fluorinated organic compounds . Combust. Sci. Technol. , 139 , 385 – 402 .
  • Tsang , W. and Lifshitz , A. ( 1998 ) Kinetic stability of 1,1,1-trifluoroethane . Int. J. Chem. Kinet. , 30 , 621 – 627 .
  • Tschuikow-Roux , E. and Quiring , W.J. (1971) Kinetics of the thermally induced dehydrofluorination of 1,1,1-trifluoroethane in shock waves. J. Phys. Chem. , 75, 295–300.
  • Tschuikow-Roux , E. , Millward , G.E. , and Quiring , W.J. ( 1971 ) Kinetics of the shock wave pyrolysis of pentafluoroethane . J. Phys. Chem. , 75 , 3493 – 3498 .
  • Zegers , E.J.P. and Fisher , E.M. ( 1996 ) Gas-phase pyrolysis of diethyl methylphosphonate . Combust. Sci. Technol. , 116–117 , 69 – 89 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.