335
Views
39
CrossRef citations to date
0
Altmetric
Original Articles

An Experimental Study of the Structure of a Stoichiometric Ethanol/Oxygen/Argon Flame

, &
Pages 519-532 | Published online: 23 Jan 2008

REFERENCES

  • Agarwal , A.K. ( 2007 ) Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines . Prog. Energy Comb. Sci. , 33 , 233 – 271 .
  • Barnard , J.A. and Hughes , H.W.D. ( 1960 ) The pyrolysis of ethanol . Trans. Faraday Soc. , 56 , 55 – 63 .
  • Brown , J. and Tipper , C.F.H. ( 1969 ) The cool flame combustion of ethanol . Proc. Royal Soc. , A312 , 399 – 415 .
  • Burcat , A. ( 2007 ) Ideal Gas Thermodynamic Data in Polynomial form for Combustion and Air Pollution Use. http://garfield.chem.elte.hu/Burcat/burcat.html .
  • Cooke , D.F. , Dodson , M.G. and Williams , A. ( 1971 ) A shock-tube study of the ignition of methanol and ethanol with oxygen . Combust. Flame , 16 , 233 – 236 .
  • Curran , H.J. , Dunphy , M.P. , Simmie , J.M. , Westbrook , C.K. , and Pitz , W.J. ( 1992 ) Shock tube ignition of ethanol, isobutene and MTBE: Experiment and modeling . Proc. Combust. Instit. , 24 , 769 – 776 .
  • Dagaut , P. , Boettner , J.C. , and Cathonnet , M. ( 1992 ) Kinetic modeling of ethanol pyrolysis . J. Chim. Phys. , 89 , 867 – 884 .
  • Dias , V. , Renard , C. , Van Tiggelen , P.J. , and Vandooren , J. ( 2003 ) Modeling of soot precursors in rich premixed Ethylene/Oxygen/Argon flames . Proc. of European Combustion Meeting , paper 214 .
  • Dunphy , M.P. and Simmie , J.M. ( 1991a ) High-temperature oxidation of ethanol Part 1. Ignition delays in shock waves . J. Chem. Soc. Faraday Trans. , 87 ( 11 ), 1691 – 1696 .
  • Dunphy , M.P. , Patterson , M.P. , and Simmie , J.M. ( 1991b ) High-temperature oxidation of ethanol Part 2. Kinetic modelling . J. Chem. Soc. Faraday Trans. , 87 ( 16 ), 2549 – 2559 .
  • Dutton , N.J. , Fletcher , I.W. , and Whitehead , J.C. ( 1985 ) Dynamics of hydrogen atom abstraction in the reaction O(3P) + ethanol . J. Phys. Chem. , 89 , 569 – 570 .
  • Egolfopoulos , F.N. , Du , D.X. , and Law , C.L. ( 1992 ) A study on ethanol oxidation kinetics in laminar premixed flames, flow reactors and shock tubes . Proc. Combust. Instit. , 24 , 833 – 841 .
  • Ergut , A. , Granata , S. , Jordan , J. , Carlson , J. , Howard , J.B. , Richter , H. , and Levendis , Y.A. ( 2006 ) PAH formation in one-dimensional premixed fuel-rich atmospheric pressure ethylbenzene and ethyl alcohol flames . Combust. Flame , 144 , 757 – 772 .
  • Grotheer , H.H. , Nesbitt , F.L. , and Klemm , R.B. (1986) Absolute rate constant for the reaction of O(3P) with ethanol. J. Phys. Chem. , 90, 2512–2518.
  • Gülder , O.L. ( 1982 ) Laminar burning velocities of methanol, ethanol and isooctane-air mixture . Proc. Combust. Instit. , 19 , 275 – 281 .
  • Hess , W.P. and Tully , F.P. ( 1989 ) Hydrogen-atom abstraction from methanol by OH . J. Phys. Chem. , 93 , 1944 – 1947 .
  • Hill , J. , Nelson , E. , Tilman , D. , Polasky , S. , and Tiffany , D. ( 2006 ) Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels . Proc. Nat. Acad. Sci. USA , 103 ( 30 ), 11206 – 11210 .
  • Inal , F. and Senkan , S.M. ( 2002 ) Effects of oxygenate additives on polycyclic aromatic hydrocarbons . Combust. Sci. Tech. , 174 ( 9 ), 1 – 19 .
  • Kee , R.J. , Rupley , F.M. , and Miller , J.A. ( 1989 ) CHEMKIN-II: A Fortran Chemical Kinetics Package for the Analysis of Gas-Phase Chemical Kinetics, Technical Report SAND89-8009, Sandia National Laboratories .
  • Kent , J.H. ( 1970 ) A noncatalytic coating for platinum-rhodium thermocouples . Combust. and Flame , 14 , 279 – 282 .
  • Kerr , J.A. and Parsonage , M.J. ( 1976 ) Evaluated Kinetic Data on the Gas Phase Hydrogen Transfer Reactions of Methyl Radicals , Butterworths , London , p. 98 .
  • Li , J. , Kazakov , A. , and Dryer , F.L. ( 2004 ) Experimental and numerical studies of ethanol decomposition reaction . J. Phys. Chem. A , 108 , 7671 – 7680 .
  • Li , J. , Kazakov , A. , and Dryer , F.L. ( 2005 ) Chemical kinetics of ethanol oxidation . Proc. of the European Combustion Meeting , paper 019 .
  • Lieb , D.F. and Roblee , Jr. , L.H.S. ( 1970 ) A radioisotopic tracer study of carbon formation in ethanol-air diffusion flames . Combust. Flame , 14 , 285 – 296 .
  • Mahnen , G. ( 1973 ) Ph D. Thesis Université Catholique de Louvain , Belgium.
  • Marinov , N.M. ( 1999 ) A detailed chemical kinetic model for high temperature ethanol oxidation . Int. J. Chem. Kinet. , 31 , 183 – 220 .
  • McEnally , C.S. and Pfefferle , L.D. ( 2007 ) The effects of dimethyl ether and ethanol on benzene and soot formation in ethylene nonpremixed flames . Proc. Combust. Instit. , 31 , 603 – 610 .
  • Natarajan , K. and Bhaskaran , K.A. ( 1981 ) An experimental and analytical investigation of high temperature ignition of ethanol , International Symp. On Shock Tubes and Waves , 13 , 834 – 842 .
  • Norton , T.S. and Dryer , F.L. ( 1990 ) The flow reactor oxidation of C1–C4 Alcohols and MTBE . Proc. Combust. Instit. , 23 , 179 – 185 .
  • Norton , T.S. and Dryer , F.L. ( 1992 ) An experimental and modeling study of ethanol oxidation kinetics in an atmospheric pressure flow reactor . Int. J. Chem. Kinet. , 24 , 319 – 344 .
  • Pitz , W.J. , Wilk , R.D. , Westbrook , C.K. , and Cernansky , N.P. ( 1988 ) The oxidation of N-butane at low and intermediate temperatures: An experimental and modeling study , Western States Section, The Combustion Institute, Spring meeting , 38 .
  • Rotzoll , G. ( 1985 ) High-temperature pyrolysis of ethanol . J. Anal. Appl. Pyrol. , 9 ( 1 ), 43 – 52 .
  • Sawyer , R.F. ( 1992 ) Reformulated gasoline for automotive emissions reduction . Proc. Combust. Instit. , 24 , 1423 – 1432 .
  • Smith , S.R. and Gordon , A.S. ( 1956 ) Studies of diffusion flames. II. Diffusion flames of some simple alcohols . J. Phys. Chem. , 60 , 1059 – 1062 .
  • Tanoff , M.A. , Schear , D.M. , Olsson , J.O. , and Andersson , L.A. ( 1992 ) Combustion of ethanol in laminar flames: probing with continuous microprobe sampling mass spectrometry . Bull. Soc. Chim. Belg. , 101 , 839 – 850 .
  • Tsang , W. ( 1976 ) Thermal stability of alcohols . Int. J. Chem. Kinet. , 8 , 173 – 192 .
  • Vandooren , J. , Branch , M.C. , and Van Tiggelen , P.J. 1992. Comparisons of the structure of stoichiometric CH4-N2O-Ar and CH4-O2-Ar flames by molecular beam sampling and mass spectrometric analysis. Combust. Flame , 90, 247–258.
  • von Blottnitz , H. and Curran , M.A. ( 2007 ) A review of assessments conducted on bio-ethanol as a transportation fuel from a net energy, greenhouse gas, and environmental life cycle perspective . J. Clean. Prod. , 15 , 607 – 619 .
  • Walker , R.W. ( 1975 ) A Specialist Periodical Report, Reaction Kinetics , Vol. 1 , The Chemical Society , London ; ( 1977 ) Gas Kinetics and Energy Transfer , The Chemical Society , London , Vol. 2 .
  • Wu , J. , Song , K.H. , Litzinger , T. , Lee , S.Y. , Santoro , R. , Linevsky , M. , Colket , M. , and Liscinsky , D. ( 2006 ) Reduction of PAH and soot in premixed ethylene-air flames by addition of ethanol . Combust. Flame , 144 , 675 – 687 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.