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Original Articles

Solid Oxide Fuel Cells: Operating Principles, Current Challenges, and the Role of Syngas

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Pages 1207-1244 | Published online: 09 May 2008

REFERENCES

  • Adler , S. ( 2004 ) Factors governing oxygen reduction in solid oxide fuel cell cathodes . Chem. Rev. , 104 , 4791 – 4843 .
  • Aguilar , L. , Zha , S. , Li , S. , Winnick , J. , and Liu , M. ( 2004 ) Sulfur-tolerant materials for the hydrogen sulfide SOFC . Electrochem. Solid State Lett. , 7 , A324 – 326 .
  • Alcaide , F. , Cabot , P. , and Brillas , E. ( 2006 ). Fuel cells for chemicals and energy cogeneration . J. Power Sources , 153 , 47 – 60 .
  • Aravind , P. , Ouweltjes , J. , deHeer , J. , Woudstra , N. , and Rietveld , G. ( 2005 ) Impact of biosyngas and its components on sofc anodes . In Singhal , S. and Mizusaki , J. (Eds.) Solid Oxide Fuel Cells IX, Electrochemical Society , Pennington , NJ , USA , pp. 1459 – 1467 .
  • Athanassiou , C. , Pekridis , G. , Kaklidis , N. , Kalimeri , K. , Vartzoka , S. , and Marnellos , G. ( 2007 ) Hydrogen production in solid electrolyte membrane reactors (SEMRs) . Int. J. Hydrogen Energy , 32 , 38 – 54 .
  • Atkinson , A. , Barnett , S. , Gorte , R. , Irvine , J. , McEvoy , A. , Mogensen , M. , Singhal , S. , and Vohs , J.M. (2004) Advanced anodes for high-temperature fuel cells. Nature Mater. , 3, 17–27.
  • Baron , S. , Brandon , N. , Atkinson , A. , Steele , B. , and Rudkin , R. ( 2004 ) The impact of wood-derived gasification gases on Ni-CGO anodes in intermediate temperature solid oxide fuel cells . J. Power Sources , 126 , 58 – 66 .
  • Brandon , N. , Skinner , S. , and Steel , B. ( 2003 ) Recent advances in materials for fuel cells . Ann. Rev. Mater. Res. , 33 , 183 – 213 .
  • Cheng , Z. , Zha , S. , Aguilar , L. , Wang , D. , Winnick , J. , and Liu , M. ( 2006a ) A solid oxide fuel cells running on H2S/CH4 fuel mixtures . Electrochem. Solid State Lett. , 9 , A31 – A33 .
  • Cheng , Z. , Zha , S. , and Liu , M. ( 2006b ) Stability of materials as candidates for sulfur-resistant anodes of solid oxide fuel cells . J. Electrochem. Soc. , 153 , A1302 – A1309 .
  • Fergus , J. ( 2006 ) Electrolytes for solid oxide fuel cells . J. Power Sources , 162 , 30 – 40 .
  • Fleig , J. ( 2003 ) Solid oxide fuel cell cathodes: Polarization mechanisms and modeling of the electrochemical performance . Ann. Rev. Mater. Res. , 33 , 361 – 382 .
  • Fleig , J. ( 2005 ) On the current-voltage characteristics of charge transfer reactions at mixed conducting electrodes on solid electrolytes . Phys. Chem. Chem. Phys. , 7 , 2027 – 2037 .
  • Gemmen , R. and Trembly , J. ( 2006 ) On the mechanisms and behavior of coal syngas transport and reaction within the anode of a solid oxide fuel cell . J. Power Sources , 161 , 1084 – 1095 .
  • Gubner , A. , Nguyen-Xuan , T. , Bram , M. , Remmel , J. , and de Harrt , L. ( 2006 ) Lightweight cassette type SOFC stacks for automotive applications. European Fuel Cell Forum, Luzern, Switzerland, Paper B042 .
  • Gupta , G. , Dean , A. , Ahn , K. , and Gorte , R. ( 2006a ) Comparison of conversion and deposit formation of ethanol and butane under SOFC conditions . J. Power Sources , 158 , 497 – 503 .
  • Gupta , G. , Hecht , E. , Zhu , H. , Dean , A. , and Kee , R. ( 2006b ) Gas-phase reactions of methane and natural-gas with air and steam in non-catalytic regions of a solid-oxide fuel cell . J. Power Sources , 156 , 434 – 447 .
  • Gupta , G. , Marda , J. , Dean , A. , Colclasure , A. , Zhu , H. , and Kee , R. ( 2006c ) Performance predictions of a tubular SOFC operating on a partially reformed JP-8 surrogate . J. Power Sources , 162 , 553 – 562 .
  • He , H. , Vohs , J. , and Gorte , R. ( 2003 ) Effect of synthesis conditions on the performance of Cu-CeO2-YSZ anodes in SOFCs . J. Eiectrochem. Soc. , 150 , A1470 – 1475 .
  • Hecht , E. , Gupta , G. , Zhu , H. , Dean , A. , Kee , R. , Maier , L. , and Deutschmann , O. ( 2005 ) Methane reforming kinetics within a Ni-YSZ SOFC anode . Appl. Catal. A , 295 , 40 – 51 .
  • Hickman , D. and Schmidt , L. ( 1993 ) Syngas formation by direct catalytic oxidation of methane . Science , 259 , 343 – 346 .
  • Holtappels , P. , de Harrt , L. , Stimming , U. , Vinke , I. , and Mogensen , M. ( 1999 ) Reaction of CO/CO2 gas mixtures on Ni-YSZ cermet electrodes . J. Appl. Electrochem. , 29 , 561 – 568 .
  • Huang , K. , Wan , J. , and Goodenough , J. ( 2001 ) Oxide-ion conducting ceramics for solid oxide fuel cells . J. Mater. Sci. , 36 , 1093 – 1098 .
  • Ishihara , T. , Yamada , T. , Akbay , T. , and Takita , Y. ( 1999 ) Partial oxidation of methane over fuel cell type reactor for simultaneous generation of synthesis gas and electric power . Chem. Eng. Sci. 54 , 1535 – 1540 .
  • Janardhanan , V. and Deutschmann , O. ( 2006 ) CFD analysis of a solid oxide fuel cell with internal reforming: Coupled interactions of transport, heterogeneous catalysis and electrochemical processes . J. Power Sources , 162 , 1192 – 1202 .
  • Jensen , K. , Wallenberg , R. , Chorkendorff , I. , and Mogensen , M. ( 2003 ) Effect of impurities on structural and electrochemical properties of the Ni-YSZ interface . Solid State Ionics , 160 , 27 – 37 .
  • Jiang , S. and Chan , S. (2004) A review of anode materials development in solid oxide fuel cells. J. Mater. Sci. , 39, 4405–4439.
  • Jiang , Y. and Vikar , A. ( 2003 ) Fuel composition and diluent effect on gas transport and performance of anode-supported SOFCs . J. Electrochem. Soc. , 150 , A942 – A951 .
  • Kee , R. , Coltrin , M. , and Glarborg , P. ( 2003 ) Chemically Reacting Flow: Theory and Practice , John Wiley , New York .
  • Kee , R. , Zhu , H. , and Goodwin , D. ( 2004 ) Solid-oxide fuel cells with hydrocarbon fuels . Proc. Combust. Instit. , 30 , 2379 – 2404 .
  • Kee , R. , Zhu , H. , and Goodwin , D. ( 2005a ) Modeling electrochemistry and solid-oxide fuel cells: I. Basic principles . J. Combust. Soc. Japan , 47 , 192 – 204 .
  • Kee , R. , Zhu , H. , and Goodwin , D. ( 2005b ) Modeling electrochemistry and solid-oxide fuel cells: II. Research challenges . J. Combust. Soc. Japan , 47 , 276 – 289 .
  • Kim , H. , Vohs , J. , and Gorte , R. ( 2001 ) Direct oxidation of sulfur-containing fuels in a solid oxide fuel cell . Chem. Commun. , 22 , 2334 – 2335 .
  • Krishnan , V. , Mclntosh , S. , Gorte , R. , and Vohs , J. ( 2004 ). “Measurement of electrode overpotentials for direct hydrocarbon conversion fuel cells . Solid State Ionics , 166 , 191 – 197 .
  • Lin , Y. , Zhan , Z. , and Barnett , S. ( 2006 ) Improving the stability of direct-methane solid oxide fuel cells using anode barrier layers . J. Power Sources , 158 , 1313 – 1316 .
  • Liu , J. , Madsen , B.D. , Ji , Z. , and Barnett , S.A. ( 2002 ) A fuel-flexible ceramic-based anode for solid oxide fuel cell . Electrochem. Solid State Lett. , 539 , A122 – A124 .
  • Liu , Y. , Primdahl , S. , and Mogensen , M. ( 2003 ) Effects of impurities on microstructure in Ni/YSZ-YSZ half-cells for SOFC . Solid State Ionics , 161 , 1 – 10 .
  • Lu , C. , Worrell , W. , Vohs , J. , and Gorte , R. ( 2003 ) A comparison of Cu-ceria-SDC and Au-ceria-SDC composites for SOFC anodes . J. Electrochem. Soc. , 150 , A1357 – A1359 .
  • Lundberg , W. , Veyo , S. , and Moeckel , M. ( 2003 ) A high-efficiency solid oxide fuel cell hybrid power system using the mercury 50 advanced turbine systems gas turbine . J. Eng. Gas Turb. Power Trans. ASME , 125 , 51 – 58 .
  • Marnellos , G. and Stoukides , M. ( 2004 ) Catalytic studies in electrochemical membrane reactors . Solid State Ionics , 175 , 597 – 603 .
  • Mason , E. and Malinauskas , A. ( 1983 ) Gas Transport in Porous Media: The Dusty-Gas Model , American Elsevier , New York .
  • Matsuzaki , Y. and Yasuda , I. ( 2000a ) Electrochemical oxidation of H2 and CO in a H2-H2O-CO-CO2 system at the interface of a Ni-YSZ cermet electrode and YSZ electrolyte . J. Electrochem. Soc. , 147 , 1630 – 1635 .
  • Matsuzaki , Y. and Yasuda , I. ( 2000b ) The poisoning effect of sulfur-containing impurity gas on a SOFC anode: Part I. Dependence on temperature, time, and impurity concentration . Solid State Ionics , 132 , 261 – 269 .
  • McIntosh , S. and Gorte , R. ( 2004 ) Direct hydrocarbon solid oxide fuel cells . Chem. Rev. , 104 , 4845 – 4865 .
  • McIntosh , S. , He , H. , Lee , S. , Costa-Nunes , O. , Krishnan , V. , Vohs , J. , and Gorte , R. ( 2004 ) An examination of carbonaceous deposits in direct-utilization SOFC anodes . J. Electrochem. Soc. , 151 , A604 – A608 .
  • Omosun , A. , Bauen , A. , Brandon , N. , Adjiman , C. , and Hart , D. ( 2004 ) Modelling system efficiencies and costs of two biomass-fuelled SOFC systems . J. Power Sources , 131 , 96 – 106 .
  • Ormerod , R. ( 2003 ) Solid oxide fuel cells . Chem. Soc. Rev. , 32 , 17 – 28 .
  • Ouweltjes , J. , Aravind , P. , Woudstra , N. , and Rietveld , G. ( 2006 ) Biosyngas utilization in solid oxide fuel cells with Ni/GDC anodes . J. Fuel Cell Sci. Technol. , 3 , 495 – 498 .
  • Peters , R. , Dahl , R. , Klttgen , U. , Palm , C. , and Stolten , D. ( 2002 ) Internal reforming of methane in solid oxide fuel cell systems . J. Power Sources , 106 , 238 – 244 .
  • Sammes , N. , Du , Y. , and Bove , R. (2005) Design and fabrication of a 100 W anode supported micro-tubular SOFC stack. J. Power Sources , 145, 428–434.
  • Sasaki , K. and Maier , J. ( 2000 ) Re-analysis of defect equilibria and transport parameters in Y2O3-stabilized ZrO2 using EPR and optical relaxation . Solid State Ionics , 134 , 303 – 321 .
  • Sasaki , K. and Teraoka , Y. ( 2003 ) Equilibria in fuel cell gases . J. Electrochem. Soc. , 150 , A878 – A888 .
  • Schmidt , L. , Klein , E. , Leclerc , C. , Krummenacher , J. , and West , K. ( 2003 ) Syngas in millisecond reactors: higher alkanes and fast lightoff . Chem. Eng. Sci. , 58 , 1037 – 1041 .
  • Schneider , L. , Martin , C. , Bultel , Y. , Bouvard , D. , and Siebert , E. ( 2006 ) Discrete modelling of the electrochemical performance of SOFC electrodes . Electrochimica Acta , 52 , 314 – 324 .
  • Semin , G. , Belyaev , V. , Demin , A. , and Sobyanin , V. ( 1999 ) Methane conversion to syngas over Pt-based electrode in a solid oxide fuel cell reactor . Appl. Catal. A: Gen. , 181 , 131 – 137 .
  • Serra , J. , Uhlenbruck , S. , Meulenberg , W. , Buchkremer , H. , and Stover , D. ( 2006 ) Nano structuring of solid oxide fuel cells cathodes . Topics Catal. , 40 , 123 – 131 .
  • Shao , Z. and Haile , S. ( 2004 ) A high performance cathode for the next generation solid-oxide fuel cells . Nature , 431 , 170 – 173 .
  • Sheng , C. and Dean , A. ( 2004 ) The importance of gas-phase kinetics within the anode channel of a solid-oxide fuel cell . J. Phys. Chem. , 108 , 3772 – 3783 .
  • Sobyanin , V. and Belyaev , V. ( 2000 ) Gas-phase electrocatalysis: methane oxidation to syngas in a solid oxide fuel cell reactor . Solid State Ionics , 136–137 , 747 – 752 .
  • Sobyanin , V. , Belyaev , V. , and Galvita , V. ( 1998 ) Syngas production from methane in an electrochemical membrane reactor . Catal. Today , 42 , 337 – 340 .
  • Steele , B. ( 1999 ) Fuel-cell technology: Running on natural gas . Nature , 400 , 619 – 621 .
  • Sukeshini , A. , Habibzadeh , B. , Becker , B. , Pomfret , M. , Demircan , O. , Walker , R. , Eichhorn , B. , and Jackson , G. ( 2005 ) CO and CH4 electrochemical oxidation on Ni patterned anodes . In: Singhal , S. and Mizusaki , J. (Eds.), Solid Oxide Fuel Cells IX , Electrochemical Society , Pennington , NJ , USA , pp. 1294 – 1303 .
  • Sukeshini , A. , Habibzadeh , B. , Becker , B. , Stoltz , C. , Eichhorn , B. , and Jackson , G. ( 2006 ) Electrochemical oxidation of H2, CO, and CO/H2 mixtures on patterned Ni anodes on YSZ electrolytes . J. Electrochem. Soc. , 153 , A705 – A715 .
  • Sundmacher , K. , Rihko-Struckmann , L. , and Galvita , V. ( 2005 ) Solid electrolyte membrane reactors: status and trends . Catal. Today , 104 , 185 – 199 .
  • Suwanwarangkul , R. , Croiset , E. , Entchev , E. , Charojrochkul , S. , Pritzker , M. , Fowler , M. , Douglas , P. , Chewathanakup , S. , and Mahauldom , H. ( 2006 ) Experimental and modeling study of solid oxide fuel cell operating with syngas fuel . J. Power Sources , 161 , 308 – 322 .
  • Weber , A. and Ivers-Tiffee , E. ( 2004 ) Materials and concepts for solid oxide fuel cells (SOFCs) in stationary and mobile applications . J. Power Sources , 127 , 273 – 283 .
  • Weber , A. , Sauer , B. , Muller , A. , Herbstritt , D. , and Ivers-Tiffee , E. ( 2002 ) Oxidation of H2, CO and methane in SOFCs with Ni/YSZ-cermet anodes . Solid State Ionics , 152–153 , 543 – 550 .
  • Zha , S. , Moore , A. , Abernathy , H. , and Liu , M. ( 2004 ) GDC-based low-temperature SOFCs powered by hydrocarbon fuels . J. Electrochem. Soc. , 151 , A1128 – A1133 .
  • Zhan , Z. and Barnett , S. ( 2005a ) An octane-fueled solid oxide fuel cell . Science , 308 , 844 – 847 .
  • Zhan , Z. , Lin , Y. , and Barnett , S. ( 2005 ) Anode catalyst layers for direct hydrocarbon and internal reforming SOFCs . SOFC IX , 9 , 1321 – 1330 .
  • Zhan , Z. , Lin , Y. , Pillai , M. , Kim , I. , and Barnett , S. ( 2006 ) High-rate electrochemical partial oxidation of methane in solid oxide fuel cells . J. Power Sources , 161 , 460 – 465 .
  • Zhan , Z. , Liu , J. , and Barnett , S. ( 2004 ) Operation of anode-supported solid oxide fuel cells on propane-air mixtures . Appl. Catal. A. , 262 , 255 – 259 .
  • Zhang , X. , Robertson , M. , Yick , S. , Deces-Petit , C. , Styles , E. , Qu , W. , Xie , Y. , Hui , R. , Roller , J. , Kesler , O. , Maric , R. , and Ghosh , D. (2006) Sm0.5Sr0.5CoO3 + Sm0.2Ce0.8O1.9 composite cathode for cermet supported thin Sm0.2Ce0.8O1.9 electrolyte SOFC operating below 600°C. J. Power Sources , 160, 1211–1216.
  • Zhao , F. and Virkar , A. ( 2005 ) Dependence of polarization in anode-supported solid oxide fuel cells on various cell parameters . J. Power Sources , 141 , 79 – 95 .
  • Zhu , H. , Colclasure , A. , Kee , R. , Lin , Y. , and Barnett , S. ( 2006 ) Anode barrier layers for tubular solid-oxide fuel cells with methane fuel streams . J. Power Sources , 161 , 413 – 419 .
  • Zhu , H. and Kee , R. ( 2006 ) Thermodynamics of SOFC efficiency and fuel utilization as functions of fuel mixtures and operating conditions . J. Power Sources , 161 , 967 – 964 .
  • Zhu , H. and Kee , R. ( 2007a ) The influence of current collection on the performance of tubular anode-supported SOFC cells . J. Power Sources , 169 , 315 – 326 .
  • Zhu , H. and Kee , R. ( 2007b ) Modeling distributed charge-transfer processes in membrane electrode assemblies with mixed-conducting composite electrodes . SOFC-X , 10 , 1869 – 1878 .
  • Zhu , H. , Kee , R. , Janardhanan , V. , Deutschmann , O. , and Goodwin , D. ( 2005 ) Modeling elementary heterogeneous chemistry and electrochemistry in solid-oxide fuel cells . J. Electrochem. Soc. , 152 , A2427 – A2440 .

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