Kinetics of Hydrogen Oxidation—Part 4. Inhibition and Catalysis at High Degrees of Conversion

References

• Adler , J. , and Vortmyer , D. ( 1963 ). The effect of axial diffusion processes on the optimum yield of tubular reactors—1. Isothermal reactors with simple reversible reaction A≈C. Chemical Engineering Science , 18 , 99 .
   Google Scholar
• Allara , D. L. , and Edelson , D. ( 1977 ). A computational analysis of chemical switch mechanism. Catalysis-inhibition effects in coppersurface-catalized oxidation. J. Phys. Chem. , 81 , 2443 .
   Google Scholar
• Altenkirch , R. A. , Eichhorn , R. , Hsu , N. N. , Brancic , A. B. , and Cevallos , N. E. ( 1976 ). Characteristics of laminar gas jet diffusion flames under the influence of elevated gravity. Sixteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p. 1165 .
   Google Scholar
• Altenkirch , R. A. , Eichhorn , R. , and Brancic , A. B. ( 1977 ). Buoyancy induced extinction of laminar gas jet diffusion flames. Presented at the Central States Section , The Combustion Institute, Meeting at NASA Lewis Research Center.
   Google Scholar
• Alvares , N. J. ( 1975 ). CF3Br suppression of turbulent,class-B fuel fires. In Gann, R. G. (Ed.), Halogenated Fire Suppressants , ACS Symp. Ser., No. 16, 94 – 117 .
   Google Scholar
• Bajpai , S. N. ( 1974 ). An investigation of the extinction of diffusion flames by halons. J. Fire and Flammability , 5 , 255 .
   Google Scholar
• Baulch , D. L. , Drysdale , D. D. , Horne , D. G. , and Lloyd , A, C. ( 1972 ). Evaluated Kinetic Data for High-Temperature Reactions , Vol. 1 , Butterworths.
   Google Scholar
• Bennett , J. E. , and Blackmore , D. R. ( 1971 ). Rates of gas-phase hydrogen-atom recombination at room temperature in the presence of added gases. Thirteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p. 51 .
   Google Scholar
• Bonne , U. , Jost , W. , and Wagner , H. G. ( 1962 ). Iron pentacarbonyl in methane-oxygen (or air) flames. Fire Research Abstracts and Reviews , 4 , 6 .
   Google Scholar
• Brown , N. J. ( 1975 ). Halogen kinetics pertinent to flame inhibition: a review. In Gann , R. G. (Ed.), Halogen-ated Fire Suppressants, ACS Symp. Ser. ,. No. 16, 341 – 375 .
   Google Scholar
• Bulewicz , E. M. , and Padley , P. J. ( 1971 a). Catalytic effect of metal additives on free radical recombination rates in H2+ O2+N2 flames. Thirteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p. 73 .
   Google Scholar
• Bulewicz , E. M. , and Padley , P. J. ( 1971 b). Photometric investigations of the behaviour of chromium additives in premixed H2+O2+N2 flames. Proc. Roy. Soc. Lond. , A323 , 377 .
   Google Scholar
• Cochran , T. H. , and Masica , W. J. ( 1971 ). An investigation of gravity effects on laminar gas-jet diffusion flames. Thirteenth Symposium (International) on Combustion , The Combustion Institute, :Pittsburgh, Pennsylvania , p. 821 .
   Google Scholar
• Cohen , N. , Giedt , R. R. , and Jacobs , T. A. ( 1973 ). Further studies on the dissociation of HBr behind shock waves. Int. J. Chem. Kinetics , 5 , 425 .
   Google Scholar
• Cotton , D. H. , and Jenkins , D. R. ( 1971 ). Catalysis of radical-recombination reactions in flames by alkaline earth metals. Trans. Far. Soc. , 67 , 730 .
   Google Scholar
• Creitz , E. C. ( 1961 ). Inhibition of diffusion flames by methyl bromide and trifluoromethyl bromide applied to the fuel and oxygen sides of the reaction zone. J. Res. of Nat. Bur. Stand. , 65 A, 389.
   Google Scholar
• Creitz , E. C. ( 1970 ). A literature survey of the chemistry of flame inhibition. J. Res. of Nat. Bur. Stand. , 74A , 521 .
   PubMedGoogle Scholar
• Cullis , C. F. , Fish , A. , and Ward , R. B. ( 1963 ). The influence of bromine compounds on combustion processes. Proc. Roy. Soc. Land. , vA276, 527.
   Google Scholar
• Cullis , C. F. , and Mulcahy , M. F. R. ( 1972 ). The kinetics of combustion of gaseous sulphur compounds. Combustion and Flame , 18 , 225 .
   Web of Science ®Google Scholar
• DcGraff , B. A. , and Lang , K. J. ( 1970 ). Gas-phase recombination of bromine atoms. J. Phys. Client. , 74 , 4181 .
   Google Scholar
• Durie , R. A. , Johnson , G. M. , and Smith , M. Y. ( 1971 ). The effect of sulfur dioxide on hydrogen-atom recombination in the burnt gasof premixed fuel-rich propanc-oxygen-nitrogen flames. Combustion and Flame , 17 , 197 .
   Google Scholar
• Edelman , R. B. , Fortune , O. F. , Weilerstein , G. , Cochran , T. H. , and Haggard , Jr., J. B. ( 1973 ). An analytical and experimental investigation of gravity effects upon laminar gas jet-diffusion flames. Fourteenth Symposium ,{International) on Combustion,| The Combustion Institute, Pittsburgh , Pennsylvania , p. 399 .
   Google Scholar
• Fielding , G. H. , Woods , F. J. , and Johnson , J. E. ( 1975 ). Halon1301: mechanism of failure to extinguish deep-seated fire , J. Fireand Flammability , 6 , 37 .
   Google Scholar
• Ford , C. L. ( 1975 ). An overview of halon 1301 systems. In Gann, R. G. (Ed.), Halogenated Fire Suppressants , ACS Symp. Ser., No. 16, 1 – 63 .
   Google Scholar
• Friedman , R. , and Levy , J. B. ( 1957 ). Survey fundamental knowledge of mechanisms of action of flame-extinguishing agents. Tech. Rep. , 56 – 568 .
   Google Scholar
• Friedman , R. , and Levy , J. B. ( 1963 ). Inhibition of opposed-jet methane-air diffusion flames. The effects of alkali metal vapours and organic halides. Com-bustion and Flame , 7 , 195 .
   Web of Science ®Google Scholar
• Friedman , R. ( 1971 ). The role of chemistry in fire problems: gas-phase combustion kinetics. Fire Res. Abst. Reu. , 13 , 187 .
   Google Scholar
• Fristrom , R. M. , and Sawyer , R. F. ( 1971 ). Flame inhibition chemistry. Presented at AGARD (NATO) 37th Propulsion Panel Meeting. ,
   Google Scholar
• Gann , R. G. ( 1975 ). Initial reactions in flame inhibition by halogenated hydrocarbons. In Gann , R. G. (Ed.), Halogenated Fire Suppressants, ACS Symp. Ser. , No. 16, 318 – 340 .
   Google Scholar
• Getzinger , R. W. , and Blair , L. S. ( 1969 ). Recombination in the hydrogen-oxygen reaction: a shock tube study with nitrogen and water vapour as third bodies. Combustion and Flame , 13 , 271 ,
   Web of Science ®Google Scholar
• Giddings , J. C. , and Hirschfelder , J. O. ( 1957 ). Flame properties and the kinetics of chain-branching reactions. Sixth Symposium (International) on Combustion , Reinhold , New York, p. 199 .
   Google Scholar
• Halstead , C. J. , Jenkins , D. R. ( 1969 ). Radical recombination inrich premixed hydrogen/oxygen flames. Twelfth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p. 979 .
   Google Scholar
• Haslie , J. W. ( 1973 ). Molecular basis of flame inhibition. J. Res. Nat. Bur. Stand. , 77 A, 733.
   Google Scholar
• Hastie , J. W. ( 1975 ). Nigh Temperature Vapors , Academic Press, s:N.Y., pp. 332 – 357 .
   Google Scholar
• Hertzberg , M. , Johnston , A. L. , Kuchta , J. M. , and Furno , A. L. ( 1976 ). The spectral radiance growth flame temperatures, and flammability behavior of large-scale, spherical, combustion waves. Sixteenth Sym-posium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p. 767 .
   Google Scholar
• Hofmann , H. , and Astheimer , H. -J. ( 1963 ). Der Einfluss der Vermischung bei heterogenen Reaktionen in kontinuierlich betriebenen isotherm arbeitenden Rohr-reaktoren. Chemical Engineering Science , 18 , 643 .
   Google Scholar
• Homann , K. H. , and Poss , R. ( 1972 ). The effect of pressure on the inhibition of ethylene flames. Combustion and Flame , 18 , 300 .
   Web of Science ®Google Scholar
• Horie , O. , and Frazier , Jr., G. C. ( 1971 ). Recombination of bromine atoms in a laminar hydrogen-bromine flame. J. Phys. Client. , 75 , 3046 .
   Google Scholar
• Kallend , A. S. ( 1972 ). Kinetics of the sulphur dioxide catalized recombination of radicals in hydrogen flames. Combustion and Flame , 19 , 227 .
   Google Scholar
• Kaskan , W. E. ( 1958 ). Hydroxyl concentrations in rich hydrogen-air flames held on porous burners. Combustion and Flame , 2 , 229 , 286.
   Web of Science ®Google Scholar
• Kent , J. H. , and Williams , F. A. ( 1974 ). Extinction of laminar diffusion flames for liquid fuels. Fifteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p.3l 5.
   Google Scholar
• Kondratiev , V. N. ( 1970 ). Konstanty Skorosti Gazofaz-nykh Reaktsii , Moscow , Nauka .
   Google Scholar
• Kurylo , M. J. ( 1972 ). Absolute rate constant for the reaction H+ O2+M→HO2+M over the temperature range 203–404 K. J. Phys. Chem. , 76 , 3518 .
   Web of Science ®Google Scholar
• Kuvshinoff , B. W. ( 1977 ). Fire Sciences Dictionary. , New York , Wiley—Interscience Publication.
   Google Scholar
• Lovachev , L. A. ( 1960 ). The theory of flame propagation in branched and unbranched chain systems. Combustion and Flame , 4 , 357 .
   Google Scholar
• Lovachev , L. A. , Martem'yanova , T. M. , Gontkovskaya , V. T. , and Denisov , E. T. ( 1971 ). Estimation of optimal operation conditions of chemical flow reactors. Izv. Akad. Nauk. SSSR, Khim. , p. 1403 .
   Google Scholar
• Lovachev , L. A. , Gontkovskaya , V. T. , and Ozerkovskaya , N. I. ( 1972 ). Kinetics of hydrogen oxidation. Izv. Akad. Nauk. SSSR, Khim. , p. 1920 .
   Google Scholar
• Lovachev , L. A. , Babkin , V. S. , Bunev , V. A. ,} V'yun, A. V., and Krivulin , V. N. ( 1973 ). Flammability limits: an invited review. Combustion and Flame , 20 , 259 .
   Web of Science ®Google Scholar
• Lovachev , L. A. ( 1976 ). On flame propagation in vortices. Combustion and Flame , 27 , 125 .
   Web of Science ®Google Scholar
• Lovachev , L. A. , Gontkovskaya , V. T. , and Ozerkovskaya , N. I. ( 1977 ). Kinetics of hydrogen oxidation. Part 2: Hydrogen bromide bothas inhibitor and catalyst of self-ignition. Combustion Science andTechnology , 17 , 143 .
   Web of Science ®Google Scholar
• Lovachev , L. A. , and Lovachev , L. N. ( 1978 ). Kinetics of hydrogen oxydation. Part 3: Catalysis with hydrogen bromide. Combustion and Science Technology , 18 , 191 .
   Web of Science ®Google Scholar
• McHale , E. T. ( 1969 ). Survey of vapor phase chemical agents for combustion suppression. Fire Res. Abstr. Rev. , 11 , 90 .
   Google Scholar
• Miller , J. A. , and Kee , R. J. ( 1977 ). Chemical non-equilibrium effects in hydrogen-air laminar jet diffusion flames. J. Phys. Chem. , 81 , 2534 .
   Web of Science ®Google Scholar
• Milne , T. A. , Green , C. L. , and Benson , D. K. ( 1970 ). The use of the counterflow diffusion flame in studies of inhibition effectiveness of gaseous and powdered agents. Combustion and Flame , 15 , 255 .
   Google Scholar
• Morrison , M. E. , and Scheller , K. ( 1972 ). The effect of burning velocity inhibitors on the ignition of hydro-carbon-oxygen-nitrogen mixture. Combustion and Flame , 18 , 3 .
   Web of Science ®Google Scholar
• Nettleton , M. A. , and Stirling , R. ( 1974 ). The influence of additives on the burning of clouds of coal particles in shocked gases. Combustion and Flame , 22 , 407 .
   Web of Science ®Google Scholar
• Nettleton , M. A. ( 1977 ). Shock-wave chemistry in dusty gases and fogs: A review. Combustion and Flame , 28 , 3 .
   Web of Science ®Google Scholar
• Rosser , W. A. , Wise , H. , and Miller , J. ( 1959 ). Mechanism of combustion inhibition by compounds containing halogen. Seventh Symposium (International) on Combustion , Butterworths , London , p. 175 .
   Google Scholar
• Sawyer , R. F. , and Glassman , I. ( 1969 ). The reactions of hydrogen with nitrogen dioxide, oxygen, and mixtures of oxygen and nitric oxide. Twelfth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh , Pennsylvania , p. 469 .
   Google Scholar
• Seshadri , K. , and Williams , F. A. ( 1975 ). Effects of CF3Br on counter-flow combustion of liquid fuel with diluted oxygen. In Gann, R. G. (Ed.), Halogenated Fire Suppressants , ACS Symp. Ser., No. 16, 149 – 182 .
   Google Scholar
• Shui , V. H. , Appleton , J. P. , and Keck , J. C. ( 1971 ). The three-body recombination and dissociation of diatomic molecules: a comparison between theory and experi-ment. Thirteenth Symposium ,{International) on Combustion,| The Combustion Institute, Pittsburgh , Pennsylvania , p. 21 .
   Google Scholar
• Skinner , G. B. ( 1961 ). Survey of chemical aspects of flame extinguishment , ASD Technical Report 61–408. ,
   Google Scholar
• Skinner , G. B. ( 1962 ). Survey of recent research on flame extinguishment , ASD-TR-61–408, Supplement 1. ,
   Google Scholar
• Skinner , G. B. ( 1964 ). Survey of recent research on flame extinguishment , ASD-TR-61–408, Supplement 2. ,
   Google Scholar
• Spalding , D. B. ( 1956 ). The theory of name phenomena with a chainreaction. Phil. Trans. Roy. Soc. Lond. , vA249, pp. 1 – 25 .
   Google Scholar
• V'yun , A. V. ( 1975 ). Experimental investigation of flame propagation and quenching at high pressures. , Thesis, Novosibirsk.
   Google Scholar