A Flow Tube Kinetics Study of Methyl Chloride Oxidation

References

• Benson , S. W. and Bose , A. N. ( 1963 ). Structural aspects of the kinetics of four‐center reactions in the vapor phase. J. Chem. Phys. , 39 ( 12 ), 3463.
   Google Scholar
• Benson , S. W. and O'Neal , H. E. ( 1970 ). Kinetic data on gas‐phase unimolecular reactions , NSRDS‐NBS 21, NBS, Washington , D .C.
   Google Scholar
• Chang , W. D. , Karra , S. B. , and Senkan , S. M. ( 1987 ). A computational study of chlorine inhibition of CO flames. Combust. Flame , 69 , 113 .
   Web of Science ®Google Scholar
• Chang , W. D. and Senkan , S. M. ( 1989 ). Detailed chemical kinetic modeling of fuel‐rich C2HCl/O2/Ar flames. Envir. Sci. Tech. , 23 , 442 .
   Web of Science ®Google Scholar
• DeMore , W. B. , Molina , M. J. , Watson , R. T. , Golden , D. M. , Hampson , R. F. , Kurylo , M. J. , Howard , C. J. , and Ravishankara , A. R. ( 1985 ). Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. JPL Publication. , 85 ( 37 ).
   Google Scholar
• Fisher , E. , Private Communication , ( 1991 ).
   Google Scholar
• Fisher , E. , and Koshland , C. P. ( 1991 ). Measurements and calculations of the post‐flame thermal destruction of CH3C1, presented at the Fall Technical Meeting , Eastern States Section of the Combustion Institute, Cornell University, Ithaca , N .Y.
   Google Scholar
• Frenklach , M. , Hsu , J. P. , Miller , D. L. , and Matula , R. A. ( 1986 ). Shock‐tube pyrolysis of chlorinated hydrocarbons: formation of soot. Combust. Flame , 64 , 141 .
   Web of Science ®Google Scholar
• Hassler , J. C. , and Setser , D. W. ( 1966 ). RRKM calculated reaction rates for chemically and thermally activated C2H5CI, I, I‐C2HCl2, and 1, 2–C2H4Cl2. J. Client. Phys. , 45 ( 9 ), 3246.
   Google Scholar
• Hassler , J. C. , Setser , D. W. , and Johnson , R. L. ( 1966 ). Chemical activation and nonequilibrium unimolecular reactions of C2H5CI2 molecules. J. Chem. Phys. , 45 ( 9 ), 3231.
   Google Scholar
• Hung , S. L. , Barresi , A. , and Pfefferle L. D. ( 1990 ) Flow tube reactor studies of catalytically stabilized combustion of methyl chloride. Twenty‐Third Symposium (International) on Combustion. , The Combustion Institute, 909.
   Google Scholar
• Hung , S. L. ( 1991 ). The catalytically stabilized thermal combustion of methyl chloride, PhD thesis , Yale University.
   Google Scholar
• Karra , S. B. , Gutman , and Senkan , S. M. ( 1988 ). Chemical kinetic modeling of fuel‐rich CH3CI/CH4/02/Ar flames. Comb. Sci. Technol. , 60 , 45 .
   Web of Science ®Google Scholar
• Karra , S. B. and Senkan , S. M. ( 1987 ). Chemical structures of sooting CH3C1/CH4/Ar and CH4/O2Ar flames. Comb. Sci. Technol. , 54 , 333 .
   Web of Science ®Google Scholar
• Karra , S. B. and Senkan , S. M. ( 1988 ). A detailed chemical kinetic mechanism for the oxidative pyrolysis of CH3Cl. Ind. Eng. Chem. Res. , 27 , 1163 ‐168.
   Web of Science ®Google Scholar
• Karra , S. B. and Senkan , S. M , ( 1988 ). Analysis of the chemically activated CH2C1/CH2C1 and CH3/CH2Cl recombination reactions at elevated temperatures using the bimolecular Quantum Rice‐Ramsperger‐Kassel (QRRK) method. Ind. Eng. Chem. Res. , 27 , 447 .
   Web of Science ®Google Scholar
• Kassem , M. and Senkan , S. M. ( 1991 ). Chemical structure of fuel‐rich, premixed, laminar flames of 1,2–C2H4C12 and CH4. Combust. Flame , 83 , 365 .
   Web of Science ®Google Scholar
• Miller , D. ( 1984 ). High temperature combustion of selected chlorinated hydrocarbons, PhD. Dissertation , Dept ME, Louisiana State University.
   Google Scholar
• Miller , D. L. , Senser , D. W. , Cundy , V. A. , and Matula , R. A. ( 1984 ). Chemical considerations in the incineration of chlorinated methanes I: methyl chloride. Hazardous Waste , 1 ( 1 ), 1.
   Google Scholar
• Miller , J. A. and Bowman , C. T. ( 1989 ). Mechanism and modeling of nitrogen chemistry in combustion. Prog. Energy Combust. Sci. , 15 , 287 .
   Web of Science ®Google Scholar
• Miller , J. A. , Mitchell , R. E. , Smooke , M. D. , and Kee , R. J. ( 1982 ). Toward a comprehensive chemical kinetic mechanism for the oxidation of acetylene: comparison of model predictions with results from flame and shock tube experiments. Nineteenth Symposium (International) on Combustion , 181.
   Google Scholar
• Park , J. Y. , Heaven , M. C. , and Gutman , D. ( 1984 ). Kinetics and mechanism of the reactions of vinyl chloride with molecular oxygen. Chem. Phys. Lett. , 104 , 469 .
   Web of Science ®Google Scholar
• Ritter , E. R. and Bozzelli , J , ( 1990 ). Kinetic study on thermal decomposition of chlorobenzene diluted in H2. J. Phys. Chem. , 94 , 2493 .
   Web of Science ®Google Scholar
• Ritter , E. R. and Bozzelli , J. ( 1990 ). Chlorobenzene and dichlorobenzene reactions in hydrogen and in hydrogen/oxygen mixtures. Haz. Waste & Haz. Materials. , 7 ( 1 ), 103.
   Google Scholar
• Ritter , E. R. and Bozzelli , J. ( 1990 ). THERM , NJ Institute of Technology.
   Google Scholar
• Ritter , E. R. , Bozzelli , J. , and Dean★ , A. M. ( 1991 ) CHEMACT, a PC based program , New Jersey Institute of Technology and Exxon★ Chemicals.
   Google Scholar
• Russell , J. J. , Seetua , J. A. , Gutman , D. , and Melius , C. F. ( 1991 ). Kinetics and thermochemistry or the equilibria CH2Cl + O2 ⇆CH2CIO2 and CHCI2 + O2 ⇆CHC12O2 , Twenty‐third Symposium (International) on Combustion , The Combustion Institute, 217.
   Google Scholar
• Senkan , S. M. ( 1982 ). Detoxication of Hazardous Waste , Ann Arbor Sci. Publishers, 61.
   Google Scholar
• Valeiras , H. , Gupta , A. K. , and Senkan , S. M. ( 1984 ). Laminar burning velocities of chlorinated hydrocarbon‐methane‐air flames. Combust. Sci. Technol. , 36 , 123 .
   Web of Science ®Google Scholar
• Weissman , M. and Benson , S. W. ( 1984 ). Pyrolysis of methyl chloride, a pathway in the chlorine‐catalyzed polymerization of methane. Int. J. Chem. Kinet. , 15 , 341 .
   Google Scholar
• Westbrook , C. K. ( 1982 ). Inhibition of hydrocarbon oxidation in laminar flames and detonations by halogenated compounds, Nineteenth Symposium (International) on Combustion , The Combustion Institute, 127.
   Google Scholar
• Westmoreland , P. R. , Howard , J. B. , Longwell , J. P. , and Dean , A. M. ( 1986 ). Prediction of rate constants for combustion and pyrolysis by bimolecular QRRK. AlChE J. , 32 , 1971 .
   Web of Science ®Google Scholar
• Westmoreland , P. R. ( 1988 ). Bimolecular QRRK program for the personal computer , Univ. of Mass. ; : Amherst .
   Google Scholar