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Original Articles

C1/C2 Chemistry in Fuel-Rich Post-Flame Gases I. Experimental Results and Pool Modelling

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Pages 199-215 | Published online: 27 Apr 2007

References

  • Bar‐Nun , A. and Dove J. E. ( 1980 ). Acetylene pyrolysis and its oxidation by water vapour behind high‐temperature shock waves. Proceedings of the Twelfth International Symposium on Shock Tubes and Waves , Magnus Press, Jerusalem ; p. 457 .
  • Becerra , R. , Canosa‐Mas , E. , Canosa‐Mas , C. E. , Frey , H. M. , and Walsh , R. ( 1987 ). Studies of methylene chemistry by laser‐induced decomposition of ketene. J. Chem. Soc. Faraday Trans. 2 , 83 , 435 .
  • Bhaskaran , K. A. , Frank , P. , and Just , Th. ( 1980 ). High Temperature Methyl Radical Reaction with Atomic and Molecular Oxygen. Proceedings of the Twelfth International Symposium on Shock Tubes and Waves , Magnus Press, Jerusalem ; p. 503 .
  • Bittner , J. D. ( 1981 ). A molecular beam mass spectrometric study of fuel‐rich and sooting benzene/oxygen flames. , Sc.D. Thesis, MIT.
  • Bittner , J. D. and Howard , J. B. ( 1982 ). Mechanism of hydrocarbon decay in fuel‐rich secondary reaction zones. Nineteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 211 .
  • Browne , W. G. , Porter R. P. , Verlin J. D. , and Clark A. H. ( 1969 ). A study of C2H2/O2 flames. Twelfth Svmposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 1035 .
  • Colket , M. B. III , Chiappetta L. , Guille R. N. , Zabeielski M. F. , and Seery D. J. ( 1982 ). Internal aerodynamics of gas sampling probes. Comb. Flame , 44 , 1 .
  • Dean , A. M. and Westmoreland , P. R. ( 1987 ). Bimolecular QRRK analysis of methyl radical reactions. Int. J. Chem. Kinet. , 19 , 207 .
  • Fenimore , C. F. and Jones , G. W. ( 1964 ). Rate of destruction of acetylene in flame gases. J. Phys. Chem. , 41 1887 .
  • Fenimore , C. P. ( 1969 ). Destruction of methane in water gas by reaction of CH3 with OH radicals. Twelfth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 463 .
  • Frank , P. , Bhaskaran , K. A. , and Just , Th. ( 1988 ). Acetylene oxidation: The reaction C2H2 + O at high temperatures. Twenty‐First Symposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 885 .
  • Frank , P. , Bhaskaran , K. A. , and Just , Th. ( 1986 ). High‐temperature reactions of triplet methylene and ketene with radicals. J. Phys. Chem. , 90 , 2226 .
  • Hidaka , Y. , Eubank , C. S. , Gardiner , W. C. , Jr , and Hwang S. M. ( 1984 ). Shock tube and modeling study of acetylene oxidation. J. Phys. Chem. , 88 , 1006 .
  • Hwang , S. M. , Gardiner , W. C. , Jr, Frenklach , M. , and Hidaka , Y. ( 1987 ). Induction zone exothermicity of acetylene ignition. Comb. Flame , 67 , 65 .
  • Kaiser , E. W. ( 1990 ). Measured and computer‐simulated hydrocarbon and OH radical profiles in fuel‐rich atmospheric‐pressure flat flames. Reactions of CH4 and C2H2. J. Phys. Chem. , 94 , 4493 .
  • Kee , R. J. , Miller , J. A. , and Jefferson , T. H. ( 1980 ). CHEMKIN: A General‐Purpose, Problem‐Dependent, Transportable Fortran Chemical Kinetics Code Package , Report No. SAND80‐003, Sandia National Laboratories, Livermore , CA .
  • Kee , R. J. , Rupley F. M. , and Miller J. A. ( 1987 ) The CHEMKIN Thermodynamic Data Base , Report No. Sand87‐215, Sandia National Laboratories, Livermore , CA .
  • Kramlich , J. C. and Malte P. C. ( 1978 ). Modeling and measurement of sample probe effects on pollutant gases drawn from flame zones. Comb. Sci. Tech. , 18 , 91 .
  • Levy J. M. , Taylor , B. R. , Longwell J. P. , and Sarofim A. F. ( 1982 ). C1 and C2 chemistry in rich mixture C2H4/air flames. Nineteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh; p. 167 .
  • Levy , J. M. and Sarofim , A. F. ( 1983 ). Higher hydrocarbon combustion. 2. Fuel rich C1/C2 mechanism. Comb. Flame , 53 , 1 .
  • Lin , C.‐Y. , Wang , H.‐T. , Lin , M. C. , and Melius , C. F. ( 1990 ). A shock tube study of the CH2O + NO2 reaction at high temperatures. Int. J. Chem. Kinet. , 22 , 455 .
  • Liu , A. , Mulac , W. A. , and Jonah , C. D. ( 1988 ). Temperature dependence of the rate constants of the reactions of OH radicals with C2H2 and C2D2 at 1 attain Ar and from 333 to 1273 K. J. Phys. Chem. , 92 , 5942 .
  • Lohr , R. and Roth , P. ( 1981 ). Shock tube measurements of the reaction behaviour of acetylene with O‐atoms. Ber. Bunsenges. Phys. Chem. , 85 , 153 .
  • Mahmud , K. and Fontijn , A. ( 1987 ). A high‐temperature photochemistry kinetics study of the reaction of O(3P) atoms with acetylene from 290 to 1510 K. J. Phys. Chem. , 91 , 1918 .
  • Michael , J. V. and Wagner , A. F. ( 1990 ). Rate constants for the reactions O + C2H2 and O + C2D2 = products, over the temperature range 850‐950 K, by the flash photolysis‐shock tube technique. Determination of the branching ratio and a further theoretical analysis. Ber. Bunsenges. Phys. Chem. , 94 , 2453 .
  • Miller , J. A. , Mitchell , R. E. , Smooke M. D. , and Kee R. J. ( 1982 ). Toward a comprehensive chemical kinetic mechanism for the oxidation of acetylene: comparison of model predictions with results from flame and shock‐tube experiments. Nineteenth Symposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 181 .
  • Miller , J. A. and Melius , C. F. ( 1988 ). A theoretical analysis of the reaction between hydroxyl and acetylene. Twenty‐Second Symposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 1031 .
  • Miller , J. A. and Bowman C. T. ( 1989 ). Mechanism and modeling of nitrogen chemistry in combustion. Progr. Energy Combust. Sci. , 15 , 287 .
  • Peeters , J. and Mahnen , G. ( 1973 ). Structure of ethylene‐oxygen flames, Reaction Mechanism and rate constants of elementary reactions. Combustion Institute European Symposium , Academic Press, London ; p. 53 .
  • Peeters , J. and Vinckier C. ( 1975 ). Production of chemi‐ions and the formation of CH and CH2 radicals in melhane‐O2 and ethylene‐O2 flames. Fifteenth Symposium (International) on Combustion. , The Combustion Institute, Pittsburgh ; p. 969 .
  • Porter , R. P. Clark , A. H. , Kaskan , W. E. , Browne , W. E. ( 1969 ), A study of hydrocarbon flames. Eleventh Symposium (International) on Combustion , The Combustion Institute, Pittsburgh ; p. 907 .
  • Smith , D. I. ( 1981 ). Probe‐induced distortions in the sampling of one‐dimensional flames. Comb. Flame , 40 , 187 .
  • Smith , G. P. , Fairchild , P. W. , and Crosley , D. R. ( 1984 ). The pressure and temperature dependence of the OH + C2H2 reaction above 800 K. J. Chem. Phys. , 81 , 2667 .
  • Taylor , B. D. ( 1984 ). Reactions of fixed nitrogen species in fuel‐rich flames , Sc.D. Thesis, MIT.
  • Temps , F. and Wagner , H.Gg. ( 1988 ). Ber. Bunsenges. Phys. Chem. , 92 , 620 .
  • Tsang , W. and Hampson , R. F. ( 1986 ). Chemical kinetic data base for combustion chemistry. Part I. Methane and related compounds. J. Phys. Chem. Ref. Data , 15 , 1087 .
  • Vandooren , J. and Van Tiggelen , P. J. ( 1977 ). Reaction mechanisms of combustion in low pressure acetylene‐oxygen flames. Sixteenth Symposium (International) on Combustion; , p. 1133 .
  • Wagner , H. Gg. and Zabel , F. ( 1971 ). Zum thermischen Zerfall von Keten in der Gasphase. Ber. Bunsenges. Phys. Chem. , 71 , 114 .
  • Warnatz , J. ( 1984 ). Rate coefficients in the C/H/O system. In W. C. Gardiner , Jr (Ed.), Combustion Chemistry , Springer‐Verlag, NY , p. 197 .
  • Woods , I. T. ( 1988 ). Hydrocarbon reactions and soot growth in fuel‐rich flames , Ph.D. Thesis, University of Sydney.
  • Woods , I. T. and Haynes B. S. ( 1991 ), In Preparation.
  • Zucrow , M. J. ( 1977 ). Gas Dynamics , J. Wiley & Sons, New York .

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