49
Views
27
CrossRef citations to date
0
Altmetric
Original Articles

Reaction Mechanism for Arornatics Formation in a Low Pressure, Premixed Acetylene-Oxygene/Argon Flame

, &
Pages 153-173 | Received 31 Mar 1994, Accepted 27 Sep 1994, Published online: 17 Apr 2007

References

  • Bastin , E. , Delfau, J. L, Reuillon , M. , Vovelle , C. and Warnatz , J. ( 1988 ). Experimental and Computational Investigation of the Structure of a Sooting C2H2–O3–Ar Flame . Twenty-Second Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 313 .
  • Bastin , E. ( 1989 ). Etude du mécanisme de formation des précurseurs des particules de suie dans des flames C2H2/O2/Ar , Thése de Doctorat de I'Université Pierre el Marie Curie .
  • Baulch , D. L. , Cobos , C. J. , Cox , R. A. , Esser , C. , Frank , P. , Just , Th. , Pilling , M. J. , Walker , R. W. and Warnatz , J. ( 1992 ). Evaulated Kinetic data for Combustion Modelling ,. J. Phys.Chem. Ref Data , 21 , No 2 .
  • Burcat , A. ( 1984 ). Table of Coefficients Sets for NASA Polynomials, Appendix C in Combustion Chemistry , ( Gardiner, W. C. Jr Ed. ), Springier-Verlag , New York .
  • Callear , A. B. and Smith , G. B. ( 1986 ). Recurring Chains Following Addition of Atomic Hydrogen to Acetylene , J. Phys, Chem. , 90 , 3229 .
  • Cohen , N. and Westberg , K. R. ( 1983 ). J. Phys. Chem. Ref. Data , 12 , No 3 , p. 531 .
  • Colket III , M. B. and Seery , D. J. ( 1989 ). The Pyrolysis of Acetylene Initiated by Acetone , Comb, and Flame , 75 , 343 .
  • Fahr , A. and Stein , S. E. ( 1988 ). Reactions of vinyl and Phenyl Radicals with Ethyne, Ethene and Benzene . Twenty-Second Symposium (International) on Combustion , The Combustion Institute , Pittsburg , p. 1023 .
  • Felder , W. and Madronich , S. ( 1986 ). High temperature Photochemistry (HTP) Kinetics and Mechanism Studies of Elementary Combustion Reactions over 300–1700 K , Combust. Sci. and Technol. , 50 , 135 .
  • Frenklach , M. and Warnatz , J. ( 1987 ), Detailed Modeling or PAH Profiles in a Sooting Low-Pressure Acetylene Flame . Combust. Sci. and Technol. , 51 , 265 .
  • Frenklach , M. and Wang , H. ( 1990 ). Detailed Modelling of Soot Particle Nucleation and Growth, Twenty-Third Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 1559 .
  • Glassman , I. ( 1988 ). Soot Formation in Combustion Processes , Twenty Second Symposium International) on Combustion , The Combustion Institute , Pittsburgh , p. 295 .
  • Haynes , B. S. and Wagner , H. Gg. ( 1981 ). Soot Formation . Prog. Energy and Comb. Sci. , 7 , p. 229 .
  • Homann , K. H. Wellmann.C. ( 1983 ). Ber. Bunsenges . Phys. Chem. , 87 , 609 .
  • Homann , K. H. ( 1984 ). Formation of large Molecules, Particulates and lions in Premixed Hydrocarbon Flames Progress and Unresolved Questions , Twentieth Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 857 .
  • Kee , R. J. , Rupley , F. M. and Miller , J. A. ( 1987 ). The Chemkin Thermodynamic Data Base , SAND1A Report , SAND87-8215. UC-4 .
  • Kiefer , J.H. , Mizcrka , L. J. , Patel , M. R. and Wei , H. C. ( 1985 ). A Shock Tube Investigation of Major Pathways in the High-Temperature Pyrolysis of Benzene , J. Phys. Chem. , 89 , 2013 .
  • Miller , J. A. , Mitchell , R. E. , Smooke , M. D. and Kee , R. J. ( 1982 ). Towards a Comprehensive Mechanism for the Oxidation of Acetylene Comparison of Model Predictions with Results from Flame and Shock Tube Experiments . Nineteenth Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 181 .
  • Miller , J. A. ( 1991 ). The Formation of Benzene in Flames . Fuel Chemistry Division , Vol. 36 , No 4 , A. C. S. Meeting , New York .
  • Miller , J. A. and Melius , C. F. ( 1992 ), Kinetic and Thermodynamic Issues in the Formation of Aromatic Compounds in Flames of Aliphatic Fuels. Comb, and Flame , 91 , 21 .
  • Paczko , G. , Lefdal , P. M. and Peters , N. ( 1986 ). Reduced Reaction Schemes for Methane, Methanol and Propane Flames , Twenty-First Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 739 .
  • Pedersen , J. O. P. , Opansky , B. J. , Leone , S. R. ( 1993 ). Laboratory Studies of Low-Temperature Reactions of C2H with C2H2 and Implications for Atmospheric Models of Titan . J. Phys. Chem. , 97 , 6822 – 6829 .
  • Peeters , J. and Mahnen , G. ( 1973 ). Structure of Ethylene-Oxygen Flames. Reaction Mechanism and Rate Constants of Elementary Reactions , First European Symposium , Sheffield , Weinberg , F. J., Ed. , p. 53 .
  • Perry , R. A. ( 1984 ). Absolute Rate Measurements for the Reaction of the OH Radical with Diacetylene over the Temperture Range of 296–688 K , Comb, and Flame , 58 , 221 .
  • Seshadri , K. , Mauss , F. , Peters , N. and Warnatz , J. ( 1990 ). A Flamelet Calculation of Benzene Formation in Coflowing Laminar Diffusion Flame . Twenty-Third Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 559 .
  • Slagle , I. R. and Gutman , D. ( 1986 ). Kinetics of the Reaction of C2H3 with Molecular Oxygen from 293 to 900 K , Twenty-First Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , p. 875 .
  • Stein , S. E. , Walker , J. A. , Suryan , M. M. and Fahr , A. ( 1990 ). A New Path to Benzene in Flames , Twenty-Third Symposium (Internationl) on Combustion , The Combustion Institute , Pittsburgh , p. 85 .
  • Timonen , R. S. , Ratajczak , E. , Gutman , D. and Wagner , A. F. ( 1987 ). The Addition and Dissociation Reaction H+CO = HCO. 2. Experimental Studies and Comparison with Theory , J. Phys. Chem. , 91 , 5325 .
  • Vinckier , C. , Schaekers , M. and Peeters , J. ( 1985 ). The Ketyl Radical in the Oxidation of Ethyne by Alomic Oxygen at 300–600 K , J. Phys. Chem. , 89 , 508 .
  • Vovelle , C. , Delfau , J. L. and Douté , C. ( 1993 ). Role of C3, and C4 Species in Benzene Formation . Joint Meeting of the British and German Sections of the Combustion Institute , Cambridge , p. 148 .
  • Warnatz , J. ( 1981 ). The Structure of Laminar Alkane, Alkene and Acetylene Flames , Eighteenth Symposium (international) on Combustion , the Combustion Institute , Pittsburgh , p. 369 .
  • Warnatz , J. , Bockhorn , H. , Moser , A. , Wenz , H. W. ( 1982 ). Experimental Investigation and Computational Simulation of Acetylene-Oxygen Flames from Near Stoechiometric to Sooting Conditions , Nineteenth Symposium (International) on Combustion , The Combustion Institute , Pittsburgh , 197 – 209 .
  • Warnatz , J. ( 1984a ). Chemistry of High Temperature Combustion of Alkanes up to Octane . Twentieth Symposium (International|y) on Combustion , The Combustion Institute , Pittsburgh , p. 845 .
  • Warnatz , J. ( 1984 b ). Rate Coefficients in the C/H/O System, Combustion Chemistry , ( Ed. Gardiner Jr., W. C ), Springler-Verlag , ( New York ) , p. 197 .
  • Warnatz , J. ( 1988 ). Personal communication. Weissman, M. A. and Benson, S. W. (1988) . Rate Parameters for the Reactions of C2H3 and C4H5 and H2 and C2H2 . J. Phys. Chem. , 92 , 4080 – 4084 .
  • Westmoreland , P. R. , Dean , A. M. , Howard , J. B. and Longwell , J. P. ( 1989 ). Forming Benzene in Flames by Chemically Activated Isomerization , J. Phys. Chem. , 93 , 8171 .
  • Wu , C. H. and Kern , R. D. ( 1987 ). Shock Study of Allene Pyrolysis , J. Phys. Chem. , 91 , 6291 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.