345
Views
13
CrossRef citations to date
0
Altmetric
Articles

Effects of B-site ion (Nb5+) substitution on the microstructure and ionic conductivity of Li0.5La0.5TiO3 solid electrolytes

, , , , &
Pages 89-96 | Received 07 Nov 2018, Accepted 09 Sep 2019, Published online: 25 Feb 2020

References

  • K. Abhilash et al., Investigations on pure and Ag doped lithium lanthanum titanate (LLTO) nanocrystalline ceramic electrolytes for rechargeable lithium-ion batteries, Ceram. Int. 39 (2), 947 (2013). DOI: 10.1016/j.ceramint.2012.07.011.
  • A. Mei et al., Enhanced ionic transport in lithium lanthanum titanium oxide solid state electrolyte by introducing silica, Solid State Ionics. 179 (39), 2255 (2008). DOI: 10.1016/j.ssi.2008.08.013.
  • T. Teranishi et al., Lithium ion conductivity of Nd-doped (Li, La)TiO3 ceramics, Solid State Ionics. 243, 18 (2013). DOI: 10.1016/j.ssi.2013.04.014.
  • T. Abe et al., Lithium ion transfer at the interface between lithium-ion-conductive solid crystalline electrolyte and polymer Electrolyte, J. Electrochem. Soc. 151 (11), A1950 (2004). DOI: 10.1149/1.1804813.
  • Y. Kobayashi et al., All-solid-state lithium secondary battery with ceramic/polymer composite electrolyte, Solid State Ionics. 152–153, 137 (2002). DOI: 10.1016/S0167-2738(02)00366-1.
  • Y. Inaguma et al., High ionic conductivity in lithium lanthanum titanate, Solid State Commun. 86 (10), 689 (1993).DOI: 10.1016/0038-1098(93)90841-A.
  • H. Geng et al., Effect of sintering atmosphere on ionic conduction and structure of Li0.5La0.5TiO3 solid electrolytes, Mater. Sci. Eng. B. 164 (2), 91 (2009). DOI: 10.1016/j.mseb.2009.07.011.
  • C. MilianPila et al., Influence of citrate/nitrate ratio on the preparation of Li0.5La0.5TiO3 nanopowder by combustion method, Ceram. Int. 40, 249 (2014). DOI: 10.1016/j.ceramint.2013.05.131.
  • H. Geng et al., Investigation of structure and electrical properties of Li0.5La0.5TiO3 ceramics via microwave sintering, J. Alloys Compd. 481 (1–2), 555 (2009). DOI: 10.1016/j.jallcom.2009.03.038.
  • A. Mei et al., Lithium lanthanum titanium oxide solid-state electrolyte by spark plasma sintering, J. Alloys Compd. 486 (1–2), 871 (2009). DOI: 10.1016/j.jallcom.2009.07.091.
  • H. Chung, J. Kim, and J. Kim, Dependence of the lithium ionic conductivity on the B-site ion substitution in (Li0.5La0.5)Ti1-xMxO3(M = Sn, Zr, Mn, Ge), Solid State Ionics. 107 (1–2), 153 (1998). DOI: 10.1016/S0167-2738(97)00525-0.
  • V. Rivera et al., Percolation-limited ionic diffusion in Li0.5-xNaxLa0.5TiO3 perovskites (0 ≤ x ≤ 0.5), Chem. Mater. 14 (12), 5148 (2002).
  • M. Sotomayor et al., Structural characterisation and Li conductivity of Li1/2−xSr2xLa1/2−xTiO3 (0 < x < 0.5) perovskites, Ceram. Int. 39, 9619 (2013).
  • T. Katsumata et al., Influence of site percolation and local distortion on lithium ion conductivity in perovskite-type oxides La0.55Li0.35-xKxTiO3 and La0.55Li0.35TiO3-KMO3, (M = Nb and Ta), Solid State Ionics. 86–88, 165 (1996).DOI: 10.1016/0167-2738(96)00116-6.
  • Q. Zhang et al. , A facile method for the synthesis of the Li0.3La0.57TiO3 solid state electrolyte, Chem. Commun. (Camb.). 50 (42), 5593 (2014).DOI: 10.1039/c4cc00335g.
  • J. Irvine, D. Sinclair, and A. West, Electroceramics: characterization by impedance spectroscopy, Adv. Mater. 2 (3), 132 (1990). DOI: 10.1002/adma.19900020304.
  • H. Le et al., Citrate gel synthesis of aluminum-doped lithium lanthanum titanate solid electrolyte for application in organic-type lithium-oxygen batteries, J. Power Sources. 274, 1188 (2015). DOI: 10.1016/j.jpowsour.2014.10.146.
  • M. E. Ling et al., Comparative study of solid-state reaction and sol-gel process for synthesis of Zr-doped Li0.5La0.5TiO3 solid electrolytes, Ionics. 22 (11), 2151 (2016). DOI: 10.1007/s11581-016-1744-8.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.