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Original Articles

Stereospecific Cyclopolymerization with Group 4 Metallocenes

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Pages 1225-1234 | Published online: 23 Oct 2006

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  • The percentage of uncyclized units was determined by integrating the 1H-NMR resonances of the olefinic hydrogens. For the lower molecular weight oligomers obtained at 80 °C, it is difficult to distinguish endgroups from uncyclized olefin in the chain, which could explain the apparent decrease in the amount of cyclization at these temperatures.
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  • For the resonance at 33.4 ppm there are four possible resonances at tetrad resolution (RmR, MmR, RrR, and MrR)

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