Polyelectrolyte Nanocomposite Membranes Using Surface Modified Nanosilica for Fuel Cell Applications

References

• Baglio, V.; Di Blasi, A.; Arico, A. S.; Antonucci, V.; Antonucci, P. L.; Fiory, F. S.; Licoccia, S.; Traversa, E. Influence of TiO2 nanometric filler on the behaviour of a composite membrane for applications in direct methanol fuel cells. J. New Mater. Electrochem. Syst. 2004, 7, 275–280.
   Web of Science ®Google Scholar
• Hickner, M. A.; Ghassemi, H.; Kim, Y. S.; Einsla, B. R.; McGrath, J. E. Alternative polymer systems for proton exchange membranes (PEMs). Chem. Rev. 2004, 104, 4587–4612.
   PubMed Web of Science ®Google Scholar
• Lufrano, F.; Baglio, V.; Di Blasi, O.; Staiti, P.; Antonucci, V.; Arico, A. S. Solid polymer electrolyte based on sulfonated polysulfone membranes and acidic silica for direct methanol fuel cells. Solid State Ion. 2012, 216, 90–94.
   Web of Science ®Google Scholar
• Zhang, H.; Huang, H.; Shen, P. K. Methanol-blocking Nafion® composite membranes fabricated by layer by layer self-assembly for direct methanol fuel cells. Int. J. Hydrogen Energy. 2012, 37, 6875–6879.
   Web of Science ®Google Scholar
• Jalili, J.; Borsacchi, S.; Tricoli, V. Proton conducting membranes in fully anhydrous conditions at elevated temperature: Effect of nitrilotris(methylenephosphonic acid) incorporation into Nafion® and poly(styrenesulfonic acid). J. Membr. Sci. 2014, 469, 169–173.
   Web of Science ®Google Scholar
• Vishnyakov, A.; Neimark, A. V. Self-assembly in Nafion® membranes upon hydration: Water mobility and adsorption isotherms. J. Phys. Chem. 2014, 38, 11353–11364.
   Web of Science ®Google Scholar
• Kosmala, B.; Schauer, J. Ion-exchange membranes prepared by blending sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) with polybenzimidazole. J. Appl. Polym. Sci. 2002, 85, 1118–1127.
   Web of Science ®Google Scholar
• Tohidian, M.; Ghaffarian, S. R.; Shakeri, S. E.; Bahlakeh, G. Sulfonated aromatic polymers and organically modified montmorillonite nanocomposite membranes for fuel cells applications. J Macromol Sci., Part B, Phys. 2013, 52, 1578–1590.
   Web of Science ®Google Scholar
• Tohidian, M.; Ghaffarian, S. R.; Shakeri, S. E.; Dashtimoghadam, E.; Hasani-Sadrabadi, M. M. Organically modified montmorillonite and chitosan–phosphotungstic acid complex nanocomposites as high performance membranes for fuel cell applications. J. Solid State Chem. 2013, 17, 2123–2137.
   Google Scholar
• Wu, H.; Shen, X.; Cao, Y.; Li, Z.; Jiang, Z. Composite proton conductive membranes composed of sulfonated poly (ether ether ketone) and phosphotungstic acid-loaded imidazole microcapsules as acid reservoirs. J Membr Sci. 2014, 451, 74–84.
   Web of Science ®Google Scholar
• Honma, I.; Yamada, M. Bio-inspired membranes for advanced polymer electrolyte fuel cells. Anhydrous proton-conducting membrane via molecular self-assembly. Bull Chem Soc Jpn. 2007, 50, 2110–2123.
   Web of Science ®Google Scholar
• Mikhailenko, S. D.; Wang, K. P.; Kaliaguine, S.; Xing, P. X.; Robertson, G. P.; Guiver, M. D. Proton conducting membranes based on cross-linked sulfonated poly(ether ether ketone) (SPEEK). J. Membr. Sci. 2004, 233, 93–99.
   Web of Science ®Google Scholar
• Neburchilov, V.; Martin, J.; Wang, H.; Zhang, J. A review of polymer electrolyte membranes for direct methanol fuel cells. J. Power Sources. 2007, 169, 221–238.
   Web of Science ®Google Scholar
• Kreuer, K. D. On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells. J. Membr. Sci. 2001, 185, 29–39.
   Web of Science ®Google Scholar
• Kreuer, K. D.; Ise, M.; Fuchs, A.; Maier, J. Proton and water transport in nano-separated polymer membranes. J. Phys. IV. 2000, 10, Pr7–Pr279.
   Google Scholar
• Quartarone, E.; Mustarelli, P.; Carollo, A.; Grandi, S.; Magistris, A. PBI composite and nanocomposite membranes for PEMFCs: The role of the filler. Fuel Cells. 2009, 3, 231–236.
   Web of Science ®Google Scholar
• Marschall, R.; Sharifi, M.; Wark, M. Proton conductivity of imidazole functionalized ordered mesoporous silica: Influence of type of anchorage, chain length and humidity. Micropor Mesopor Mat. 2009, 123, 21–29.
   Web of Science ®Google Scholar
• Rhee, C. H.; Kim, H. K.; Chang, H.; Lee, J. S. Nafion®/sulfonated montmorillonite composite: A new concept electrolyte membrane for direct methanol fuel cells. Chem. Mater. 2005, 17, 1691–1697.
   Web of Science ®Google Scholar
• Peckham, T. J.; Holdcroft, S. Structure-morphology-property relationships of non-perfl uorinated proton-conducting membranes. Adv. Mater. 2010, 22, 4667–4690.
   PubMed Web of Science ®Google Scholar
• Kawaguti, C.A.; Dahmouche, K.; Gomes, A. Nanostructure and properties of proton-conducting sulfonated poly(ether ether ketone) (SPEEK) and zirconia–SPEEK hybrid membranes for direct alcohol fuel cells: Effect of the nature of swelling solvent and incorporation of heteropolyacid. Polym. Int. 2012, 61, 82–92.
   Web of Science ®Google Scholar
• Uma, T.; Nogami, M. Structural and transport properties of mixed phosphotungstic acid/phosphomolybdic Acid/SiO2 glass membranes for H2/O2 fuel cells. Chem. Mater. 2007, 19, 3604–3610.
   Web of Science ®Google Scholar
• Xu, W.; Lu, T.; Liu, C.; Xing, W. Low methanol permeable composite Nafion®/silica/PWA membranes for low temperature direct methanol fuel cells. Electrochim Acta. 2005, 50, 3280–3585.
   Web of Science ®Google Scholar
• Staiti, P.; Arico, A. S.; Baglio, V.; Lufrano, F.; Passalacqua, E.; Antonucci, V. Hybrid Nafion®–silica membranes doped with heteropolyacids for application in direct methanol fuel cells. Solid State Ionics. 2001, 145, 101–107.
   Web of Science ®Google Scholar
• Shao, Z. G.; Joghee, P.; Hsing, I. M. Preparation and characterization of hybrid Nafion®–silica membrane doped with phosphotungstic acid for high temperature operation of proton exchange membrane fuel cells. J Membr Sci. 2004, 229, 43–51.
   Web of Science ®Google Scholar
• Dimitrova, P.; Friedrich, K. A.; Stimming, U.; Vogt, B. Modified Nafion®-based membranes for use in direct methanol fuel cells. Solid State Ionics. 2002, 150, 115–122.
   Web of Science ®Google Scholar
• Su, Y. H.; Liu, Y. L.; Sun, Y. M.; Lai, J. Y.; Wang, D. M.; Gao, Y.; Liu, B.; Guiver, M. D. Proton exchange membranes modified with sulfonated silica nanoparticles for direct methanol fuel cells. J Membr Sci. 2007, 296, 21–28.
   Web of Science ®Google Scholar
• Choi, B. G.; Hong, J.; Park, Y. C.; Jung, D. H.; Hong, W. H.; Hammond, P. T.; Park, H. Innovative polymer nanocomposite electrolytes: Nanoscale manipulation of ion channels by functionalized graphenes. ACS Nano. 2011, 5, 5167–5174.
   PubMed Web of Science ®Google Scholar
• Tohidian, M.; Ghaffarian, S. R.; Nouri, M.; Jaafarnia, E.; Haghighi, A. H. Polyelectrolyte nanocomposite membranes using imidazole-functionalized nanosilica for fuel cell applications. J Macromol Sci., Part B, Phys. 2015, 54, 17–31.
   Web of Science ®Google Scholar
• Amjadi, M.; Rowshanzamir, S.; Peighambardoust, S. J.; Sedghi, S. Preparation, characterization and cell performance of durable Nafion®/SiO2 hybrid membrane for high-temperature 1polymeric fuel cells. J Power Sources. 2012, 210, 350–357.
   Web of Science ®Google Scholar