Doping Na⁺ into Polyvinyl Alcohol: Methacrylic Acid-Ethyl Acrylate (PVA/MAA:EA) Polymer Blend Electrolytes; A Way to Improve the Blend’s Thermal, Structural, Optical and Electrical Properties

References

• Raza, S.; Li, X.; Soyekwo, F.; Liao, D.; Xiang, Y.; Liu, C. A Comprehensive Overview of Common Conducting Polymer-Based Nanocomposites; Recent Advances in Design and Applications. Eur. Poly. J. 2021, 160, 110773. DOI: 10.1016/j.eurpolymj.2021.110773.
   Web of Science ®Google Scholar
• Eterigho-Ikelegbe, O.; Yoro, K. O.; Bada, S. Coal as a Filler in Polymer Composites: A Review. Resour. Conserv. Recycl. 2021, 174, 105756. DOI: 10.1016/j.resconrec.2021.105756.
   Google Scholar
• Li, R.; Yang, X.; Li, J.; Shen, Y.; Zhang, L.; Lu, R.; Wang, C.; Zheng, X.; Chen, H.; Zhang, T. Review on Polymer Composites with High Thermal Conductivity and Low Dielectric Properties for Electronic Packaging. Mater. Today Phy. 2022, 22, 100594. DOI: 10.1016/j.mtphys.2021.100594.
   Web of Science ®Google Scholar
• Dhandapani, E.; Thangarasu, S.; Ramesh, S.; Ramesh, K.; Vasudevan, R.; Duraisamy, N. Recent Development and Prospective of Carbonaceous Material, Conducting Polymer and Their Composite Electrode Materials for Supercapacitor—A Review. J. Ener. Stor. 2022, 52, 104937. DOI: 10.1016/j.est.2022.104937.
   Google Scholar
• Siddaiah, T.; Pravakar, O.; Gopal, N. O.; Ramesh Kumar, V.; Ramu, C. Structural, Optical and Thermal Characterizations of PVA/MAA:EA Polyblend Films. Mat. Res 2018, 21, 1–11. DOI: 10.1590/1980-5373-mr-2017-0987.
   Web of Science ®Google Scholar
• Ali, F. M. Structural and Optical Characterization of [(PVA:PVP)-Cu2+] Composite Films for Promising Semiconducting Polymer Devices. J. Mol. Struct. 2019, 1189, 352–359. DOI: 10.1016/j.molstruc.2019.04.014.
   Web of Science ®Google Scholar
• Elashmawi, I. S.; Elsayed, N. H. The Role of Gold Nanoparticles in the Structural and Electrical Properties of Cs/PVP Blend. Polym. Bull. 2020, 77, 949–962. DOI: 10.1007/s00289-019-02786-z.
   Web of Science ®Google Scholar
• Rajeh, A.; Morsi, M.; Elashmawi, I. S. Enhancement of Spectroscopic, Thermal, Electrical and Morphological Properties of Polyethylene Oxide/Carboxymethyl Cellulose Blends: Combined FT-IR/DFT. Vacuum 2019, 159, 430–440. DOI: 10.1016/j.vacuum.2018.10.066.
   Web of Science ®Google Scholar
• Abdelghany, A. M.; Oraby, A. H.; Asnag, G. M. Structural, Thermal and Electrical Studies of Polyethylene Oxide/Starch Blend Containing Green Synthesized Gold Nanoparticles. J. Mol. Struct 2019, 1180, 15–25. DOI: 10.1016/j.molstruc.2018.11.095.
   Google Scholar
• Saadiah, M. A.; Zhang, D.; Nagao, Y.; Muzakir, S. K.; Samsudin, A. S. Reducing Crystallinity on Thin Film Based CMC/PVA Hybrid Polymer for Application as a Host in Polymer Electrolytes. J Non-Cryst. Sol. 2019, 511, 201–211. DOI: 10.1016/j.jnoncrysol.2018.11.032.
   Web of Science ®Google Scholar
• Vondrák, J.; Reiter, J.; Velická, J.; Sedlařı́ková, M. PMMA-Based Aprotic Gel Electrolytes. Solid State Ion 2004, 170, 79–82. DOI: 10.1016/j.ssi.2003.08.060.
   Google Scholar
• Sagane, F.; Abe, T.; Iriyama, Y.; Ogumi, Z. Li+ and Na+ Transfer through Interfaces between Inorganic Solid Electrolytes and Polymer or Liquid Electrolytes. J. Power Sources 2005, 146, 749–752. DOI: 10.1016/j.jpowsour.2005.03.075.
   Google Scholar
• Abe, T.; Sagane, F.; Ohtsuka, M.; Iriyama, Y.; Ogumi, Z. Lithium-Ion Transfer at the Interface between Lithium-Ion Conductive Ceramic Electrolyte and Liquid Electrolyte-A Key to Enhancing the Rate Capability of Lithium-Ion Batteries. J. Electrochem. Soc. 2005, 152, A2151. https://iopscience.iop.org/article/10.1149/1.2042907.
   Google Scholar
• Ragab, H. M. Spectroscopic Investigations and Electrical Properties of PVA/PVP Blend Filled with Different Concentrations of Nickel Chloride. Physica B. 2011, 406, 3759–3767. DOI: 10.1016/j.physb.2010.11.030.
   Web of Science ®Google Scholar
• Hodge, R. M.; Edward, G. H.; Simon, G. P. Water Absorption and States of Water in Semicrystalline Poly(Vinyl Alcohol) Films. Polymer 1996, 37, 1371–1376. DOI: 10.1016/0032-3861(96)81134-7.
   Web of Science ®Google Scholar
• Reddeppa, N.; Sharma, A. K.; Rao, V.; Chen, W. AC Conduction Mechanism and Battery Discharge Characteristics of (PVC/PEO) Polyblend Films Complexed with Potassium Chloride. Measurement 2014, 47, 33–41. DOI: 10.1016/j.measurement.2013.08.047.
   Web of Science ®Google Scholar
• Hareesh, K.; Sanjeev, G.; Pandey, A. K.; Rao, V. Characterization of UV-Irradiated Lexan Polycarbonate Films. Iran Polym. J. 2013, 22, 341–349. DOI: 10.1007/s13726-013-0133-7.
   Web of Science ®Google Scholar
• Reddeppa, N.; Sharma, A. K.; Rao, V. V. R. N.; Chen, W. Preparation and Characterization of Pure and KBr Doped Polymer Blend (PVC/PEO) Electrolyte Thin Films. Microelectron. Eng. 2013, 112, 57–62. DOI: 10.1016/j.mee.2013.05.015.
   Google Scholar
• Stephan, A. M.; Yuria, S.; Muniyandi, N.; Renganathan, N. G.; Kalyanasundaram, S.; Nimma Elizabeth, R. Preparation and Characterization of PVC/PMMA Blend Polymer Electrolytes Complexed with LiN(CF3SO2)2. Solid State Ion 2002, 148, 467–473. DOI: 10.1016/S0167-2738(02)00089-9.
   Web of Science ®Google Scholar
• Cottrell, T. L. The Strength of Chemical Bonds; Butterworth: London, 275, 1954.
   Google Scholar
• Hema, M.; Selvasekarapandian, S.; Nithya, H.; Sakunthala, A.; Arun Kumar, D. Structural and Ionic Conductivity Studies on Proton Conducting Polymer Electrolyte Based on Polyvinyl Alcohol. Ionics 2009, 15, 487–491. DOI: 10.1007/s11581-008-0254-8.
   Web of Science ®Google Scholar
• Kiran Kumar, K.; Ravi, K.; Pavani, Y.; Bhavani, S.; Sharma, A. K.; Narasimha Rao, V. V. R. Investigations on PEO/PVP/NaBr Complexed Polymer Blend Electrolytes for Electrochemical Cell Applications. J. Membr. Sci. 2014, 454, 200–211. DOI: 10.1016/j.memsci.2013.12.022.
   Web of Science ®Google Scholar
• Yamamoto, T.; Inami, M.; Kanbara, T. Preparation and Properties of Polymer Solid Electrolytes Using Poly(Vinyl Alcohol) and Thermally Resistive Poly[Arylene(1,3-Imidazolidine-2,4,5-Trione-1,3-Diyl)] as Matrix Polymers. Chem. Mater. 1994, 6, 44–50. DOI: 10.1021/cm00037a011.
   Web of Science ®Google Scholar