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- Note that orientational order, which is primarily determined by repulsive interations, leads to shape‐dependent attractive interactions in nematic mixtures.33 Thus the “structural” and “energetic” contributions are related
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- These exceptions have been encountered for plate‐like solutes and solutes that possibly form geometrically and energetically favored charge‐transfer complexes with the nematic phase
- “ Chapter 10 ” . Reference 33
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- Since In (γη ∞/γi ∞) = In[(VR)/(VR)n] where (VR)i and (VR)n are the net retention volumes ex-trapolated to TNI from measurements in the isotropic and nematic phases respectively, neither solute physical data nor knowledge of column liquid phase weight are needed to utilize this approach.
- Tables containing the primary data and the thermodynamic quantities obtained therefrom may be obtained directly from the author.